| PA6超微化及PA6／PP／硅灰石复合材料制备新方法 |
| |
| 引用本文： | 刘生长,王琪.PA6超微化及PA6／PP／硅灰石复合材料制备新方法[J].武汉化工学院学报,2001,23(3):35-38. |
| |
| 作者姓名： | 刘生长 王琪 |
| |
| 作者单位： | [1]武汉化工学院材料工程系，湖北武汉430073 [2]四川大学高分子研究所，四川成都610065 |
| |
| 基金项目： | 国家重点基础研究专项经费资助项目(973)(G1999064809). |
| |
| 摘 要： | 采用粒度分析，透射电镜观察，分子量测定及力学性能测试等手段研究尼龙6（PA6）及与内烯接枝马来酸酐（PP－g-MAH)和硅灰石混合的PA6在碾磨力场作用下的结构及力学性能的变化，实现了PA6的超微化，使用碾磨共混所得的PA6／PP－g-MAH／硅灰石混合微粉制备一PA6／PP硅灰石复合材料，研究表明，在碾磨力场作用下，PA6分子链发生断裂，粒度减小，最小可以达到80nm，碾磨过程中聚合物和填料之间的分散和相互作用使PA6／PP／硅灰石复合材料的力学性能增加，其屈服强度最高达到57MPa.
|
| 关 键 词： | 尼龙6 聚丙烯 粉碎 复合材料 硅灰石 制备 |
| 文章编号： | 10044736(2001)03003504 |
| 修稿时间： | 2000年6月13日 |
New method on preparing of nylon 6 micropowderand PA6/PP/wollastonite composite |
| |
| LIU Changsheng ,WANG Qi.New method on preparing of nylon 6 micropowderand PA6/PP/wollastonite composite[J].Journal of Wuhan Institute of Chemical Technology,2001,23(3):35-38. |
| |
| Authors: | LIU Changsheng WANG Qi |
| |
| Affiliation: | LIU Changsheng 1,WANG Qi 2 |
| |
| Abstract: | The structure and mechanical performance of PA6 and the PA6 mixed with PPgMAH and wollastonite induced by panmilling were studied by particle size analysis, TEM observation, viscosity average molecular weight measurement and mechanical properties testes. The results showed that the pan type milling equipment has very high efficiency in pulverizing engineering plastic PA6; wollastonite contributes to the crushing of PA6 particles and the decreasing of its molecular weight when they are ground together. The particle size of PA6 decreased to about 80 nm when PA6 was comilled with wollastonite and PPgMAH for 28 cycles of pan milling. The high mechanical performance PA6/PP/wollastonite composite was prepared using the micropowder, which was obtained by comilling PA6 with wollastonite and PPgMAH. |
| |
| Keywords: | nylon 6 polypropylene pulverizing composite |
| 本文献已被 CNKI 维普 等数据库收录！ |
