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Promotive effect of isopentane on cyclohexane isomerization catalyzed by sulfated zirconia |
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| Authors: | Kiyoyuki Shimizu Tomohito Sunagawa Keijiro Arimura Hideshi Hattori |
| Affiliation: | (1) Energy Resources Department, National Institute for Resources and Environment, AIST, 16‐3, Onogawa, Tsukuba, Ibaraki 305‐8569, Japan;(2) Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo, Noda, Chiba 278‐8510, Japan;(3) Center for Advanced Research of Energy Technology, Hokkaido University, Sapporo 060‐8628, Japan |
| Abstract: | Cyclohexane isomerization to methylcyclopentane over sulfated zirconia is markedly enhanced in the presence of isopentane which acts as a hydride transfer agent to facilitate the slow step of hydride transfer from cyclohexane to isopropyl cation. This was revealed by deuterium tracer studies. This revised version was published online in July 2006 with corrections to the Cover Date. |
| Keywords: | sulfated zirconia cyclohexane isomerization effect of solvent |
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