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MCM‐41‐supported mercapto palladium(0) complex: an efficient and recyclable catalyst for the heterogeneous Stille coupling reaction
Authors:Hong Zhao  Guomin Zheng  Wenyan Hao  Mingzhong Cai
Affiliation:1. Department of Chemistry, Jiangxi Normal University, Nanchang 330022, People's Republic of China;2. Department of Pharmacy, Guangdong Pharmaceutical College, Guangzhou 510240, People's Republic of China
Abstract:The Stille cross‐coupling reaction of organostannanes with aryl halides was achieved in the presence of a catalytic amount of MCM‐41‐supported mercapto palladium(0) complex (1 mol%) in DMF? H2O (9:1) under air atmosphere in good to high yields. This MCM‐41‐supported palladium catalyst can be reused at least 10 times without any decrease in activity. Copyright © 2009 John Wiley & Sons, Ltd.
Keywords:Stille coupling reaction  supported catalyst  mercapto palladium complex  heterogeneous catalysis
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