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Thermally stimulated shrinkage forces in oriented polymers: 1. Temperature dependence
Authors:T Pakula  M Trznadel
Affiliation:Centre of Molecular and Macromolecular Studies, Polish Academy of Science, Lód?, Poland
Abstract:Temperature dependences of shrinkage forces appearing in oriented polymer samples when heated at constant length were recorded for polycarbonate, polyethylene terephthalate, polyethylene and polypropylene. The influence of various processing conditions on thermally stimulated shrinkage forces is demonstrated. A four-state model is proposed which qualitatively describes the temperature dependences of shrinkage forces in amorphous polymers.
Keywords:thermal shrinkage  shrinkage forces  orientation  model  amorphous polymers
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