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BETA zeolite nanowire synthesis under non-hydrothermal conditions using carbon nanotubes as template
Authors:Cuong Pham-Huu  Gauthier Winé  Marc-Jacques Ledoux  Claire Marichal
Affiliation:a Laboratoire des Matériaux, Surfaces et Procédés pour la Catalyse, UMR 7515 CNRS, ECPM, Université Louis Pasteur, 25, rue Becquerel, F-67087 Strasbourg cedex 02, France
b Laboratoire des Matériaux Minéraux, UMR 7016 CNRS, ENSCMu, 3, rue Alfred Werner, F-68093 Mulhouse cedex, France
Abstract:The properties of carbon nanotubes, used as a nanometric template and as a reactor for the synthesis of BETA zeolite, have been investigated. The confinement effect of the carbon nanotubes, induced by the high aspect ratio of the tubes could be effectively used for the synthesis of one-dimensional nanowire zeolitic materials under non-hydrothermal macroscopic conditions. Zeolite material is easily recovered by combustion of the nanotubes. The average sizes of the zeolite particles are about 20 nm. The BETA zeolite was successfully used as a catalyst for benzoylation of anisol. The zeolite catalyst exhibits a high activity compared to a commercial BETA, essentially due to its high external surface area.
Keywords:A  Carbon nanotubes  B  Catalyst  C  Scanning electron microscopy  C  Transmission electron microscopy  D  Catalytic properties
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