| 8-羟基喹啉-5-磺酸构筑的有机-无机配位化合物的合成、结构和性质研究 |
| |
| 引用本文： | 王瑛,薛铭,徐家宁,朱广山,裘式纶.8-羟基喹啉-5-磺酸构筑的有机-无机配位化合物的合成、结构和性质研究[J].中国科学B辑,2009,39(10):1159-1166. |
| |
| 作者姓名： | 王瑛 薛铭 徐家宁 朱广山 裘式纶 |
| |
| 作者单位： | 吉林大学无机合成与制备国家重点实验室, 长春 130012 |
| |
| 基金项目： | 本工作得到国家重点基础研究发展计划（编号：2006CB806100）、国家自然科学基金杰出青年基金（批准号：20625102）和国家自然科学基金（批准号：20831D02,20571030,20531030,20371020）资助,特此一并致谢. |
| |
| 摘 要： | 在溶剂热条件下,以8-羟基喹啉-5-磺酸为配体,合成了两个新的有机-无机配位化合物Mn（QS）（H2O）（1）和Co（QS）（H2O）2（2）（H2QS=8-hydroxylquinoline-5-sulfonic acid）,并且对他们进行了单晶X-射线解析.其中化合物1是一个具有金红石拓扑的三维开放骨架结构,化合物2是一个三维超分子结构.我们对这些化合物进行了粉末X射线,红外光谱,差热热重,荧光光谱和磁学性质的研究.
|
| 关 键 词： | 有机-无机杂化材料 8-羟基喹啉-5-磺酸 荧光 磁性 |
| 收稿时间： | 2009-07-16 |
| 修稿时间： | 2009-08-10 |
Synthesis,crystal structure and properties of inorganic-organic hybrid polymers based on 8-hydroxylquinoline-5-sulfonic acid |
| |
| WANG Ying,XUE Ming,XU JiaNing,ZHU GuangShan,QIU ShiLun.Synthesis,crystal structure and properties of inorganic-organic hybrid polymers based on 8-hydroxylquinoline-5-sulfonic acid[J].Science in China(Series B),2009,39(10):1159-1166. |
| |
| Authors: | WANG Ying XUE Ming XU JiaNing ZHU GuangShan QIU ShiLun |
| |
| Affiliation: | ( State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130012, China) |
| |
| Abstract: | Two new inorganic-organic hybrid polymers, Mn（QS）（H2O） （1） and Co（QS）（H2O）2 （2） （H2QS=8-hydroxylquinoline-5-sulfonic acid）, based on 8-hydroxylquinoline-5-sulfonate ligand, have been synthesized under solvothermal conditions and their structures were solved by single-crystal X-ray diffraction analysis. Compound 1 is a three-dimensional open framework with rutile topology structure, and compound 2 is a three-dimensional supramolecular structure. These compounds were characterized by powder XRD, infrared spectroscopy, thermogravimetric analysis, fluorescence properties and magnetism properties. |
| |
| Keywords: | Inorganic-organic hybrid polymers 8-hydroxylquinoline-5-sulfonate Fluorescence properties Magnetism properties |
| 本文献已被 维普 等数据库收录！ |
| 点击此处可从《中国科学B辑》浏览原始摘要信息 |
|
点击此处可从《中国科学B辑》下载全文 |
|
