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K5Bi(MoO4)4-Nd3+晶体生长和光学性质
引用本文:唐连安,刘建成,陈家平,王文,乐秀宏.K5Bi(MoO4)4-Nd3+晶体生长和光学性质[J].物理学报,1985,34(5):674-680.
作者姓名:唐连安  刘建成  陈家平  王文  乐秀宏
作者单位:中国科学院上海硅酸盐研究所
摘    要:在化学计量的熔料里,用提拉法生长了K5Bi0.9Nd0.1(MoO4)4和K5Bi0.97Nd0.03(MoO4)4单晶。该晶体属于三方晶系,空间群为R3m,Z=1.5,晶胞常数为a=6.023?,c=20.887?(Nd0.1)。K5Bi(Mo 关键词

收稿时间:3/7/1984 12:00:00 AM

GROWTH AND OPTICAL PROPERTIES OF K5Bi(MoO4)4-Nd3+ SINGLE CRYSTALS
TANG LIAN-AN,LIU JIAN-CHENG,CHEN JIA-PING,WANG WEN and LE XIU-HONG.GROWTH AND OPTICAL PROPERTIES OF K5Bi(MoO4)4-Nd3+ SINGLE CRYSTALS[J].Acta Physica Sinica,1985,34(5):674-680.
Authors:TANG LIAN-AN  LIU JIAN-CHENG  CHEN JIA-PING  WANG WEN and LE XIU-HONG
Abstract:Single crystals of K5Bi0.9Nd0.1 (MoO4)4 and K5Bi0.97Nd0.03(MoO4)4 were grown from sto-ichiometric melts by the usual Czochralski technique. The crystal (Nd = 0.1) belongs to trigonal system, with space group R3m, Z = 1.5, and cell parameters a = 6.023 ?, c=20.887?.The room temperature absorption spectra of K,Bi(MoO4)4-Nd3+(3 % or 10 % Nd3+) consist of several bands characteristic of the rare earth Nd ions in crystals. The substitution of Nd3+ by Bi3+ does not affect the surrounding of the active ions. Details of room temperature emission spectra corresponding to the 4F3/24I13/2 and 4F3/24I11/2 transitions are also given.
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