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非晶态合金镀层的耐蚀性能
引用本文:姚素薇,小若正伦.非晶态合金镀层的耐蚀性能[J].天津大学学报(自然科学与工程技术版),1999,32(3):374-377.
作者姓名:姚素薇  小若正伦
作者单位:[1]天津大学化工学院 [2]日本上村工业中央研究所
摘    要:电沉积Ni-W-P非晶合金中W含量可高达55.2%,硬度为700~1100Hv,经550℃热处理,可达1300~1400Hv,镀层硬度和耐蚀性优于Ni-P非晶镀层,非晶镀层中的类金属元素P可使腐蚀电位正移,高熔点元素W可使合金镀层在酸溶液中发生钝化,有W含量越高维钝化电流密度越低;金属Cr元素除降低维钝电流密度外,还使钝化区范围加宽,孔蚀电位显著变正,浸泡实验结果表明,在30℃,1mol/L的HC

关 键 词:电沉积  非晶态合金  耐蚀性  镀层

CORROSION RESISTANCE OF AMORPHOUS ALLOY DEPOSITS
Yao,Suwei,Zhang,Weiguo,Jiang,Xiaofei,Guo,Hetong.CORROSION RESISTANCE OF AMORPHOUS ALLOY DEPOSITS[J].Journal of Tianjin University(Science and Technology),1999,32(3):374-377.
Authors:Yao  Suwei  Zhang  Weiguo  Jiang  Xiaofei  Guo  Hetong
Abstract:In the study of the corrosion resistance of amorphous electrodeposition,some elements are found to be of great importance for corrosion resistant ability.Among them are P,W and Cr.Metal like element P can improve the corrosion resistance of the deposit by moving the corrosion potential positively.W is high melting point metal,it can make the deposit passived in acid solution and the deposit passive current density decreases as the content of W in deposit increases.Metal element Cr can decrease the passive current density as well as broaden the passive potential range.It also can move the deposit pitting potential positively.Immersion tests show that the corrosion resistance of amorphous alloy is better than SUS304.
Keywords:electrodeposition  amorphous  deposits  adding  elements  high  corrosion  resistance
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