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化学沉淀法对水中钼、钴金属污染物的应急处理技术研究
引用本文:胡小芳,丁卫,张建国,袁润权,陈明. 化学沉淀法对水中钼、钴金属污染物的应急处理技术研究[J]. 供水技术, 2010, 4(1): 21-24. DOI: 10.3969/j.issn.1673-9353.2010.01.007
作者姓名:胡小芳  丁卫  张建国  袁润权  陈明
作者单位:东江水务有限公司,广东,东莞,523000
基金项目:国家水体污染控制与治理科技重大专项(2008ZX07420-005)
摘    要:通过混凝试验,研究了化学沉淀法去除钼、钴金属污染物的可行性、最佳处理条件及最大应对能力。结果表明,采用三氯化铁作混凝剂,混凝前原水pH值调至7.0~7.6,可有效去除钼,其最佳pH值为7.0,且在钼标准限值10倍浓度条件下依然有良好的去除效果,但钼标准限值50,100倍浓度条件下,混凝沉淀后上清液钼浓度均无法达标;采用聚合氯化铝作混凝剂则无法有效去除钼。采用三氯化铁和聚合氯化铝作混凝剂,混凝前将水样pH值分别调至9.6~10.0和9.25~9.5,均可有效去除钴,其最佳pH值分别为9.75和9.5;在钴标准限值10,50和100倍高浓度条件下,聚合氯化铝作为混凝剂的去除效果明显优于三氯化铁,混凝沉淀后上清液钴浓度均能达标。

关 键 词:化学沉淀法      三氯化铁  聚合氯化铝  pH

Emergency treatment technology of molybdenum and cobalt contamination with chemical precipitation in water
Hu Xiaofang,Ding Wei,Zhang Jianguo,Yuan Runquan,Chen Ming. Emergency treatment technology of molybdenum and cobalt contamination with chemical precipitation in water[J]. Water Technology, 2010, 4(1): 21-24. DOI: 10.3969/j.issn.1673-9353.2010.01.007
Authors:Hu Xiaofang  Ding Wei  Zhang Jianguo  Yuan Runquan  Chen Ming
Affiliation:Dongjiang Water Supply Co.;Ltd.;Dongguan 523000;China
Abstract:The feasibility,the optimal condition for treatment and the maximum removal efficiency of molybdenum and cobalt in water were investigated with a chemical precipitation method.The result showed that using ferric chloride as coagulant and adjusting pH of raw water to a range of 7.0~7.6 before coagulation,molybdenum could be removed effectively.The optimal pH was 7.0.It had good removal efficiency of molybdenum when the concentration was 10 times of the molybdenum water standard limit,but molybdenum in the su...
Keywords:chemical precipitation method  molybdenum  cobalt  ferric chloride  PAC  pH  
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