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掺硫NaCl晶体中(F_2~+)_H心的形成及其稳定性
引用本文:林碧洲,许承晃,邱继展,吴季怀.掺硫NaCl晶体中(F_2~+)_H心的形成及其稳定性[J].中国激光,1996,23(7):651-656.
作者姓名:林碧洲  许承晃  邱继展  吴季怀
作者单位:华侨大学材料物理化学研究所
摘    要:报道了掺硫NaCl晶体(F_2 ̄+)_H心的制备过程以及(F_2 ̄+)_H心的室温避光稳定性。讨论了S2-对F_2 ̄+的稳定作用和(P_2 ̄+)H制备过程中的缺陷化学反应.研究表明.促使F3心热分解成F心和控制好转型光的辐照剂量是制备高浓度、高纯度(F_2 ̄+)_H心材料的关键技术之一。

关 键 词:色心激光,F_2 ̄+型心,掺杂效应
收稿时间:1995/8/15

Formation and Stability of (F+2)HCenters in Sulfur-doped NaCl
Lin Bizhou, Xu Chenghuang, Qiu Jizhan, Wu Jihuai.Formation and Stability of (F+2)HCenters in Sulfur-doped NaCl[J].Chinese Journal of Lasers,1996,23(7):651-656.
Authors:Lin Bizhou  Xu Chenghuang  Qiu Jizhan  Wu Jihuai
Abstract:The preparation procedure of (F2+)H centers in sulfur-doped NaCl was describe,and the stability of (F2+)H centers in the dark at room temperature was also measured. This Paper discusses the stabilities of S2- on F2+ centers, the defect reaction during Process, and POints out that the concentration of F3 centers must be kept as lower as possible during quenching in order to obtain high concentration of (F2+)H centers. It is Proved that the transient absorption due to F2+ centers during light aggregation can not be absolutely avoided,and thus increases the no-laser-active loss. The exposure dosage during aggregation is one ofthe major controllable Paramaters to obtain a high qualitative crystal.
Keywords:color center laser  F+2-like center  dopent effect
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