Effects of sulfur poisoning on degradation phenomena in oxygen electrodes of solid oxide electrolysis cells and solid oxide fuel cells |
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Authors: | Takuto Kushi |
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Affiliation: | Energy System Research Institute, Tokyo Gas Co., Ltd., 3-13-1 Minamisenju, Arakawa-ku, Tokyo 116-0003, Japan |
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Abstract: | The durabilities of a single solid oxide electrolysis cell (SOEC) and a solid oxide fuel cell (SOFC) operating at 0.3 A cm?2 and 973 K under different air supply conditions were investigated. In the SOEC, S penetration was observed mainly at the gadolinium-doped ceria (CGO) electrolyte/lanthanum strontium cobalt oxide (LSC) oxygen electrode interface. In contrast, during SOFC operation, S was distributed widely within the LSC. The reaction governing S penetration into the LSC is an oxidizing one. Thus, it is likely that the high oxygen partial pressure at the CGO electrolyte/LSC oxygen electrode interface accelerated the penetration of S. When air was supplied using an activated carbon filter during SOEC operation, the degradation rate decreased to 0.6% kh?1 within 3000 h. Finally, the results of accelerated tests performed using air containing 0.2 ppm SO2 suggested that the effect of S poisoning was greater during SOEC operation than during SOFC operation. |
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Keywords: | SOEC SOFC High-temperature electrolysis Sulfur poisoning Durability |
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