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光助Fenton法降解水中对氨基苯酚的研究
引用本文:崔节虎,蔡洪涛.光助Fenton法降解水中对氨基苯酚的研究[J].华北水利水电学院学报,2009,30(6):99-101,105.
作者姓名:崔节虎  蔡洪涛
作者单位:1. 郑州航空工业管理学院,河南,郑州,450015;南京大学,江苏,南京,210093
2. 华北水利水电学院,河南,郑州,450011
基金项目:河南省重点科技攻关项目 
摘    要:采用光助Fenton氧化法处理对氨基苯酚模拟废水,考察了光强、Fenton试剂的用量、初始pH值、反应时间对降解效果的影响,初步探讨了其降解动力学规律.结果表明,450 W高压汞灯照射以及较强太阳光照射的条件均可以明显加快Fenton法催化氧化降解对氨基苯酚溶液的过程.Fe2+(2.5 g/L)投加量为1.0 mL,H2O2(6%)投加量为1.0 mL,初始pH值为4,太阳光照射下降解对氨基苯酚时效果较好,反应40 m in后降解率高达99%;降解过程符合准一级反应动力学方程.

关 键 词:太阳光  Fenton试剂  对氨基苯酚

Study on Degradation to P-aminophenol in Water by Photo-Fenton Technique
CUI Jie-hu,CAI Hong-tao.Study on Degradation to P-aminophenol in Water by Photo-Fenton Technique[J].Journal of North China Institute of Water Conservancy and Hydroelectric Power,2009,30(6):99-101,105.
Authors:CUI Jie-hu  CAI Hong-tao
Affiliation:CUI Jie-hu,CAI Hong-tao(1.Zhengzhou Institute of Aeronautical Industry Management,Zhengzhou 450015,China;2.Nanjing University,Nanjing 210093,China;3.North China Institute of Water Conservancy and Hydroelectric Power,Zhengzhou 450011,China)
Abstract:p-aminophenol in water was degraded by photo-Fenton technique.Effects of light intensity reaction time,Fenton reagent dosage,initial pH value on degradation of p-aminophenol were investigated.Kinetics for degradation to p-aminophenol was initially discussed too.The results show that high pressure mercury lamp with 450 W and sunlight can accelerate degradation of p-aminophenol.When pH value is 4,the volume added of Fe2+ solution is 1.0 mL with the concentration 2.5 g/L,and the volume added of H2O2 solution is 1.0 mL with the concentration 6%,and the reaction time is 40 min,the degradation rate of p-aminophenol is over 99%,the kinetics for degradation of p-aminophenol by photo-Fenton conforms with first-order reaction equation.
Keywords:sunlight  Fenton reagent  p-aminophenol
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