Reactions of [(Cp)2Ti(NCS)2] as a potential metalloligand; synthesis and physico-chemical investigations of novel heterobimetallic complexes期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Reactions of [(Cp)2Ti(NCS)2] as a potential metalloligand; synthesis and physico-chemical investigations of novel heterobimetallic complexes

Authors:	Zafar Ahmad Siddiqi Arif Ali Khan

Affiliation:	(1) Organometallic and Coordination Chemistry Research Group, Chemistry Department, Aligarh Muslim University, 202 002 Aligarh, India

Abstract:	Summary Bis(cyclopentadienyl)titanium(IV) diisothiocyanate (Cp)₂-Ti(NCS)₂] reacts with MCl₂ (M = Cu, Pd or Pt), CuCl(PPh₃)₃], RuCl₂(PPh₃)₃] and RuCl₂(DMSO)₄] (DMSO = dimethylsulphoxide) giving solid compounds of stochiometry (Cp)₂Ti(-NCS)₂MCl₂] (M = Cu, Pd or Pt), (Cp)₂Ti(-NCS)₂CuCl(PPh₃)], (Cp)₂Ti(-NCS)₂-RuCl(PPh₃)₂]Cl and (Cp)₂Ti(-NCS)₂RuCl₂(DMSO)2]. These products have been characterized by physicochemical and spectroscopic methods.

Keywords:
本文献已被 SpringerLink 等数据库收录！