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PS-b-PDMS/环氧树脂制备疏水性环氧涂层的性能
引用本文:王辰伟,张倩,李艳星,张俊然,申永亮,王月欣.PS-b-PDMS/环氧树脂制备疏水性环氧涂层的性能[J].高分子材料科学与工程,2010(3):149-152.
作者姓名:王辰伟  张倩  李艳星  张俊然  申永亮  王月欣
作者单位:河北工业大学高分子科学与工程研究所;
基金项目:河北省自然科学基金资助项目(E2008000057)
摘    要:用共混法将聚苯乙烯-b-聚二甲基硅氧烷(PS-b-PDMS)嵌段共聚物与环氧树脂E-44复合制备了一种疏水性环氧涂层。研究了PS-b-PDMS的用量对涂层力学性能、表面性能及耐化学腐蚀性的影响。结果表明,随着共聚物用量的增加,涂层的冲击强度及柔韧性明显提高,表面能显著降低,接触角明显增大,当PS-b-PDMS用量为E-44的7%(质量分数)时,冲击强度和柔韧性分别为50kg.cm和0.5mm,表面能为13.8mN/m,对水接触角增大至115.9°,具有优异的疏水性及耐化学腐蚀性。

关 键 词:聚苯乙烯-b-聚二甲基硅氧烷  环氧涂层  疏水性  耐化学腐蚀性

Characterization of Hydrophobic Epoxy Coatings Prepared by PS-b-PDMS/Epoxy Resin
WANG Chen-wei,ZHANG Qian,LI Yan-xing,ZHANG Jun-ran,SHEN Yong-liang,WANG Yue-xin.Characterization of Hydrophobic Epoxy Coatings Prepared by PS-b-PDMS/Epoxy Resin[J].Polymer Materials Science & Engineering,2010(3):149-152.
Authors:WANG Chen-wei  ZHANG Qian  LI Yan-xing  ZHANG Jun-ran  SHEN Yong-liang  WANG Yue-xin
Affiliation:The Department of Polymer Science and Engineering;Hebei University of Technology;Tianjin 300130;China
Abstract:An epoxy coating with water repellent property was prepared by blending of polystyrene-b-polydimethylsiloxane(PS-b-PDMS)and epoxy resin.The influence of different amount of PS-b-PDMS on the mechanical properties,the corrosion resisting properties and the surface performance was discussed.The results show that with the increase of PS-b-PDMS,the impact resistance and flexibility are improved,the surface energy is decreased fast,the hydrophobic properties of epoxy coatings is also improved.When the content of ...
Keywords:PS-b-PDMS  epoxy coatings  hydrophobic  anti-corrosion property  
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