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超声光催化降解苯胺及其衍生物研究
引用本文:顾浩飞,安太成,文晟,陈卫国,朱锡海,傅家谟,盛国英. 超声光催化降解苯胺及其衍生物研究[J]. 环境科学学报, 2003, 23(5): 593-597
作者姓名:顾浩飞  安太成  文晟  陈卫国  朱锡海  傅家谟  盛国英
作者单位:1. 中山大学化学与化学工程学院,广州,510275
2. 中山大学化学与化学工程学院,广州,510275;中国科学院广州地球化学研究所有机地球化学国家重点实验室,广东省环境资源利用与保护重点实验室,广州,510640
3. 中国科学院广州地球化学研究所有机地球化学国家重点实验室,广东省环境资源利用与保护重点实验室,广州,510640
基金项目:国家自然科学基金 (2 99770 30 ),广东省科学与技术计划项目 (A30 30 5 0 2 ),中国科学院广州地球化学研究所有机地球化学国家重点实验室开放基金 (OGL 2 0 0 2 10 )
摘    要:以苯胺及其衍生物为研究对象,探讨了不同有机化合物结构对超声光催化降解的影响,进一步开拓了基于超声波与TiO2光催化联合催化降解有机废水的新型深度氧化处理新技术.超声光催化技术.实验结果表明,尽管超声光催化反应对苯胺及其衍生物的降解协同效应并不是很显著,但是超声光催化反应对苯胺及其衍生物却具有较好的降解率,而且不同有机化合物结构对超声光催化反应有着较大的影响。

关 键 词:超声光 催化 降解 苯胺 衍生物 有机废水 废水处理 环境污染
文章编号:0253-2468(2003)05-0593-05
收稿时间:2002-07-26
修稿时间:2002-07-26

Sonophotocatalytic degradation of aniline and its derivatives
GU Haofei,AN Taicheng,WEN Sheng,CHEN Weiguo,ZHU Xihai,FU Jiamo and SHENG Guoying. Sonophotocatalytic degradation of aniline and its derivatives[J]. Acta Scientiae Circumstantiae, 2003, 23(5): 593-597
Authors:GU Haofei  AN Taicheng  WEN Sheng  CHEN Weiguo  ZHU Xihai  FU Jiamo  SHENG Guoying
Affiliation:School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou 510275, China,1. School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou 510275, China; 2. State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environmental Resources Utilization and Protection, Guangzhou Institute of Geochem,State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environmental Resources Utilization and Protection, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China,School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou 510275, China,School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou 510275, China,State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environmental Resources Utilization and Protection, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China and State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environmental Resources Utilization and Protection, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
Abstract:The effects of compounds with different structures on their sonophotocatalytic degradation were investigated in detail, using aniline and its derivatives as model pollutant, and a new Advanced Oxidation Processes (AOPs), sonophotocatalysis which combined the photocatalysis with ultrasonic technology, was pioneered for degrading organic pollutants. The experimental result showed that the synergetic effect was not as significant as expected, but the sonophotocatalytic technology have good COD removal efficiencies, furthermore, the compounds with different structures also played an important role in the sonophotocatalytic reaction.
Keywords:sonophotocatalysis  photocatalysis  ultrasonic  compound structure  structure reactivity
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