| 微波辐射固体酸催化合成4-芳基二氢香豆素 |
| |
| 引用本文： | 张燕,吴过,陈涛,王存德. 微波辐射固体酸催化合成4-芳基二氢香豆素[J]. 广州化工, 2010, 38(12): 94-96 |
| |
| 作者姓名： | 张燕 吴过 陈涛 王存德 |
| |
| 作者单位： | 扬州大学化学化工学院,江苏扬州225002 |
| |
| 摘 要： | 以硅胶负载硫酸为固体酸催化剂,使用微波辐射促进桂皮酸和酚类化合物的Pechmann反应合成4-芳基-3,4-二氢香豆素。通过改变微波的功率、催化剂的用量、溶剂的种类及用量等因素研究反应的最优条件。在所优选的反应条件下,获得收率为33.2%~88.0%的系列4-芳基-3,4-二氢香豆素。
|
| 关 键 词： | 香豆素 桂皮酸 固体酸催化剂 微波反应 Pechmann反应 |
Study of the Synthesis of 4-Aryl-3,4-dihydrocoumarins Catalyzed by Solid Acid (SiO2-H2SO4) under Microwave Irradiation |
| |
| ZHANG Yan,WU Gou,CHEN Tao,WANG Cun-de. Study of the Synthesis of 4-Aryl-3,4-dihydrocoumarins Catalyzed by Solid Acid (SiO2-H2SO4) under Microwave Irradiation[J]. GuangZhou Chemical Industry and Technology, 2010, 38(12): 94-96 |
| |
| Authors: | ZHANG Yan WU Gou CHEN Tao WANG Cun-de |
| |
| Affiliation: | (School of Chemistry and Chemical Engineering,Yangzhou University,Jiangsu Yangzhou 225002,China) |
| |
| Abstract: | Some 4-aryl-3,4-dihydrocoumarins were synthesized via Pechmann reaction from phenols and substituted cinnamic acids in the presence of solid acid（（SiO2）n-OSO3H） under microwave irradiation.The influence of reaction conditions on yields was also tested using the reaction of cinnamic acid and phenol as a model reaction,and the optimum conditions were obtained.In the optimum conditions,the desired products were obtained in the yield of 33.2%~88.0%. |
| |
| Keywords: | coumarin cinnamic acid solid acid catalyst microwave reaction Pechmann reaction |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
