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用相图原理研究玻璃结构和性质(Ⅲ) 核磁共振谱研究钠硼钒、钾硼磷、钾硼铝和钠硼镁玻璃结构
引用本文:姜中宏,唐永兴.用相图原理研究玻璃结构和性质(Ⅲ) 核磁共振谱研究钠硼钒、钾硼磷、钾硼铝和钠硼镁玻璃结构[J].光学学报,1991(9).
作者姓名:姜中宏  唐永兴
作者单位:中国科学院上海光学精密机械研究所,中国科学院上海光学精密机械研究所 上海 201800,上海 201800
摘    要:本文运用相图模型方法,通过电子计算机计算了Na_2O-B_2O_3-V_2O_5,K_2O-B_2O_3-P_2O_5,K_2O-B_2O_3-Al_2O_3和Na_2O-B_2O_3-MgO三元系统玻璃的NMR数据,比较了实验值和计算得出的硼四配位分数(N4),得到了满意的结果。

关 键 词:相图模型  玻璃结构  硼四配位分数

Properties and structures studies of borate glasses using phase diagram method III. NMR study of glass structures for Na_2O-B_2O_3-V_2O_5,K_2O-B_2O_3-P_2O_5,K_2O-B_2O_3-Al_2O_3 and Na_2O-B_2O_3-MgO systems
JIANG ZHONGHONG AND TANG YONGXING.Properties and structures studies of borate glasses using phase diagram method III. NMR study of glass structures for Na_2O-B_2O_3-V_2O_5,K_2O-B_2O_3-P_2O_5,K_2O-B_2O_3-Al_2O_3 and Na_2O-B_2O_3-MgO systems[J].Acta Optica Sinica,1991(9).
Authors:JIANG ZHONGHONG AND TANG YONGXING
Abstract:The NMR data (N4) have been calculated using phase diagram method for the glass systems of Na2O-B2O3-V2O5, K2O-B2O3-P2O5, K2O-B2O3-Al2O3 and Na2O-B2O3-MgO. The comparison between experimental values and calculated values has been made and found they are in good agreement. In this paper, the uses of phase diagram model in glass structural study are developed.
Keywords:the principle of phase diagram  the structures of borate glass  the four-coordinated fraction of boron    
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