Cu[(PPh3)2O](acac): Cu charge-compensated by a coordinating acac anion |
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Authors: | Yi-Ming Xie Ji-Huai Wu |
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Affiliation: | aCollege of Materials Science and Engineering, Huaqiao University, Quanzhou, Fujian 362021, PR China |
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Abstract: | A complex Cu[(PPh3)2O](acac)[(PPh3)2O = Bis(2-diphenyl-phosphinophenyl) ether; acac = acetylacetone] was obtained by solution reactions and structurally characterized. The title complex is characterized by an isolated structure. X-ray structure analysis of the title complex shows that acac and (PPh3)2O behave as chelating ligands. Photoluminescent investigation reveals that the title complex displays a strong blue-light emission. |
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Keywords: | Copper Crystal structure Diketone Photoluminescence |
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