Polymeric absorbent for water sorption based on chemically crosslinked poly (acrylamide/2-acrylamido-2-methyl-1-propanesulfonic acid sodium salt) hydrogels |
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Authors: | Ömer Bar?? Üzüm Semiha Kundakc? Erdener Karada? |
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Affiliation: | (1) Fen-Edebiyat Faculty, Chemistry Department, Adnan Menderes University, 09010 Aydın, Turkey |
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Abstract: | Summary Swelling equilibrium of polyelectrolyte copolymer gels containing of acrylamide (AAm) and 2-acrylamido-2-methyl-1-propanesulfonic
acid sodium salt (AMPS) have been studied as a function of copolymer composition. AAm/AMPS hydrogels were prepared by free
radical solution polymerization in aqueous solution of AAm with AMPS as anionic comonomer and two multifunctional crosslinkers
such as ethylene glycol dimethacrylate (EGDMA) and trimethylolpropane triacrylate (TMPTA). Swelling experiments were performed
in water at 25 °C, gravimetrically. The influence of AMPS content in hydrogels was examined. Swelling of AAm/AMPS hydrogels
was increased up to 1018% (for containing 2% AMPS and crosslinked by EGDMA) 15246% (for containing 8% AMPS and crosslinked
by TMPTA), while AAm hydrogels swelled up to 804% (crosslinked by TMPTA)–770% (crosslinked by EGDMA). The values of equilibrium
water content of the hydrogels are 0.8851–0.9935. Diffusion behavior was investigated. Water diffusion into hydrogels was
found to be non-Fickian in character. |
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