| 3,3,′4,4′-偶氮苯四甲酸配合物的合成、结构与表征 |
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| 引用本文： | 王军,谢斌,何锡阳,王涛.3,3,′4,4′-偶氮苯四甲酸配合物的合成、结构与表征[J].四川轻化工学院学报,2010(5):572-575. |
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| 作者姓名： | 王军 谢斌 何锡阳 王涛 |
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| 作者单位： | [1]四川理工学院功能材料研究所,四川自贡643000 [2]四川理工学院化学与制药工程学院,四川自贡643000 |
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| 基金项目： | 四川理工学院学校科研基金项目（2009xjkpL003） |
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| 摘 要： | 合成了3,3,′4,4′-偶氮苯四甲酸（H4L）及锰的配合物Mn2L（H2O）10].4H2O,并用元素分析、荧光光谱、XRD粉末衍射和单晶衍射仪对它们进行了表征。研究结果表明化合物H4L.2H2O通过O-H…O氢键的作用构成2D的网络结构;配合物Mn2L（H2O）10].4H2O中心锰离子为六配位,其中溶剂分子水和配体L均参与配位,分子间通过O-H…O氢键构成了1D的Z字链结构,而1D链之间通过O-H…O和O-H…N形成2D的网络结构。配合物具有很好的荧光特性。
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| 关 键 词： | 3 3 ′4 4′-偶氮苯四甲酸 配合物 晶体结构 氢键 荧光光谱 |
Syntheses,Structure and Properties of Coordination Polymer Constructed Through Azobenzenetetracarboxylic Acid |
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| WANG Jun,XIE Bin,HE Xi-Yang,WANG Tao.Syntheses,Structure and Properties of Coordination Polymer Constructed Through Azobenzenetetracarboxylic Acid[J].Journal of Sichuan Institute of Light Industry and Chemical Technology,2010(5):572-575. |
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| Authors: | WANG Jun XIE Bin HE Xi-Yang WANG Tao |
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| Affiliation: | 1.Institute of Functionalized Materials,Sichuan University of Science ＆ Engineering,Zigong 643000,China;2.School of Chemistry and Pharmaceutical Engineering,Sichuan University of Science ＆ Engineering,Zigong 643000,China) |
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| Abstract: | A compound 3,3＇,4,4＇-Diazenediyldiphthalic acid（H4L） and the manganese（II） complex Mn2L（H2O）10]·4H2O were synthesized in water solution and characterized by elemental analysis,XRD,single crystal X-ray diffraction and fluorescence spectrum.The structure of H4L·2H2O exhibits interesting two-dimensional networks through the O-H…O bonds.The complex Mn2L（H2O）10]·4H2O was six-coordinated forms which included the solvent water molecules and one-dimensional Z chain and two-dimensional networks were formed by hydrogen bonds.It has been proved that the complex has fluorescence behavior. |
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| Keywords: | 3 3＇ 4 4＇-Diazenediyldiphthalic acid complex crystal complex hydrogen bonds fluorescence spectrum |
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