| 掺杂镧的固体碱MgO/SBA-15催化大豆油制备生物柴油 |
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| 引用本文： | 黄振旭,陈凌霞,王潘婷,李颖欣,贾潘潘,张文慧.掺杂镧的固体碱MgO/SBA-15催化大豆油制备生物柴油[J].化工新型材料,2020,48(3):232-235. |
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| 作者姓名： | 黄振旭 陈凌霞 王潘婷 李颖欣 贾潘潘 张文慧 |
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| 作者单位： | 郑州师范学院化学化工学院,郑州450044,郑州师范学院化学化工学院,郑州450044,郑州师范学院化学化工学院,郑州450044,郑州师范学院化学化工学院,郑州450044,郑州师范学院化学化工学院,郑州450044,郑州师范学院化学化工学院,郑州450044 |
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| 基金项目： | 河南省高等学校重点科研项目;郑州地方高校市级大学生创新训练计划项目;郑州师范学院教学改革研究项目 |
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| 摘 要： | 采用浸渍法制备了掺杂镧的固体碱MgO/SBA-15催化剂,将其用于大豆油酯交换制备生物柴油的反应。XRD表征结果显示,活性组分在载体SiO2骨架中高度分散。考察了不同镧镁物质的量比、焙烧温度和催化剂用量等因素对催化剂性能的影响,发现镧的引入有利于催化剂与反应物的接触,从而提高催化剂的活性;镧和镁物质的量之比为0.5∶1,催化剂焙烧温度700℃,焙烧时间3h,催化剂质量分数为3%,反应时间3h时,生物柴油的产率达到95%以上。
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| 关 键 词： | 掺杂镧 生物柴油 固体碱 MgO/SBA-15 |
Study on La-doped MgO/SBA-15 solid base catalyst for transesterification of soybean oil to biodiesel |
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| Huang Zhenxu,Chen Lingxia,Wang Panting,Li Yingxin,Jia Panpan,Zhang Wenhui.Study on La-doped MgO/SBA-15 solid base catalyst for transesterification of soybean oil to biodiesel[J].New Chemical Materials,2020,48(3):232-235. |
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| Authors: | Huang Zhenxu Chen Lingxia Wang Panting Li Yingxin Jia Panpan Zhang Wenhui |
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| Affiliation: | (College of Chemistry and Chemical Engineering,Zhengzhou Normal University,Zhengzhou 450044) |
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| Abstract: | The La-doped MgO/SBA-15 solid base catalysts were prepared by the immersion method and used in the transesterification of soybean oil with methanol.The catalysts were characterized by XRD.XRD showed that the active components were highly dispersed on the silica skeleton.The effects of the different La/Mg molar ratio,calcination temperature and catalyst dosage were investigated.The adding of lanthanum promoted that catalysts had higher activity.The results indicated that La/Mg molar ratio of 0.5∶1,the calcination temperature of 700℃,the calcination time of 3 h,the mass ratio of catalyst to oil of 3%,reaction time of 3 h,and the biodiesel yield can reach up to 95%. |
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| Keywords: | La-doping biodiesel solid base MgO/SBA-15 |
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