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软锰矿协同氧化浸出硫化渣回收锰钴镍工艺研究
引用本文:曾军,叶有明,陈进中,农永萍,谢雪珍,蔡井泉. 软锰矿协同氧化浸出硫化渣回收锰钴镍工艺研究[J]. 有色金属(冶炼部分), 2020, 0(10): 23-27
作者姓名:曾军  叶有明  陈进中  农永萍  谢雪珍  蔡井泉
作者单位:桂林理工大学材料科学与工程学院,广西科技师范学院食品与生化工程学院,桂林理工大学材料科学与工程学院,广西科技师范学院食品与生化工程学院,广西科技师范学院食品与生化工程学院,桂林理工大学材料科学与工程学院
基金项目:柳州柳东新区科学研究与技术开发计划基金项目(柳东科攻2018000009)
摘    要:以电解二氧化锰过程中硫化除重金属的硫化渣为原料,基于热力学分析结果,以稀硫酸为浸出剂,辅以软锰矿协同氧化浸出硫化渣,以回收其中的锰、钴、镍有价金属。考察了矿渣比、始酸浓度、液固比、反应温度对锰、钴、镍浸出率的影响。结果表明,适宜条件为:温度363.15 K、矿渣比0.08、始酸浓度90 g/L、反应时间180 min,锰、钴、镍的浸出率分别为93.5%、87.4%、86.3%。

关 键 词:硫化渣;氧化浸出;热力学;Mn;Co;Ni
收稿时间:2020-06-23
修稿时间:2020-06-26

Study on Recovery of Mn, Co, Ni from Sulfide Slag by Collaborative Oxidation Leaching with Soft Manganese Ore
ZENG Jun,YE You-ming,CHEN Jin-zhong,NONG Yong-ping,XIE Xue-zhen and CAI Jing-quan. Study on Recovery of Mn, Co, Ni from Sulfide Slag by Collaborative Oxidation Leaching with Soft Manganese Ore[J]. Nonferrous Metals(Extractive Metallurgy), 2020, 0(10): 23-27
Authors:ZENG Jun  YE You-ming  CHEN Jin-zhong  NONG Yong-ping  XIE Xue-zhen  CAI Jing-quan
Affiliation:College of materials science and engineering, guilin university of technology,School of food and biochemical engineering, guangxi normal university of science and technology,,,,
Abstract:Applying vulcanized slag of heavy metals removal by sulfurization during electrolytic manganese dioxide as raw material, dilute sulfuric acid as leaching agent, and based on thermodynamic analysis, Mn, Co and Ni were recovered by collaborative oxidation leaching with soft manganese ore. Effects of slag ratio, initial acid concentration, L/S, and reaction temperature on leaching rate of Mn, Co and Ni were investigated. The results show that leaching rate of Mn, Co and Ni is 93.5%, 87.4% and 86.3% respectively under the conditions including temperature of 363.15 K, slag ratio of 0.08, initial acid concentration of 90 g/L, and reaction time of 180 min.
Keywords:sulfide slag   oxidation leaching   thermodynamics   Mn   Co   Ni
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