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载体孔结构与三效催化剂起燃特性实验研究
引用本文:贺小昆,栾 浩,刘沁曦,计永波,孙加林.载体孔结构与三效催化剂起燃特性实验研究[J].稀有金属材料与工程,2011,40(7):1220-1224.
作者姓名:贺小昆  栾 浩  刘沁曦  计永波  孙加林
作者单位:1. 昆明理工大学,云南昆明,650093;昆明贵研催化剂有限责任公司,云南昆明,650106
2. 昆明贵研催化剂有限责任公司,云南昆明,650106
3. 昆明理工大学,云南昆明,650093
基金项目:国家高技术研究发展规划(“863”计划)(2006AA03Z462; 2008AA11A114)
摘    要:采用不同孔密度载体分别负载不同贵金属含量、不同涂层涂敷量制备系列三效催化剂,通过模拟计算和发动机台架试验研究了具有不同孔结构载体的催化剂性能.结果表明,提高载体孔密度可明显改善催化剂的起燃特性和空燃比特性、有效降低催化剂中贵金属用量、提高HCs转化效率.起燃温度变化取决于孔密度和贵金属含量间的协同作用;载体孔密度变化对...

关 键 词:三效催化剂  载体  孔结构  起燃特性
收稿时间:2010/7/18 0:00:00

Study on Relationship between Substrate Pore Structure and Emission Light-off Characteristics of Three-Way Catalysts
He Xiaokun,Luan Hao,Liu Qinxi,Ji Yongbo and Sun Jialin.Study on Relationship between Substrate Pore Structure and Emission Light-off Characteristics of Three-Way Catalysts[J].Rare Metal Materials and Engineering,2011,40(7):1220-1224.
Authors:He Xiaokun  Luan Hao  Liu Qinxi  Ji Yongbo and Sun Jialin
Affiliation:Kunming Science & Technology University, Kunming 650093, China
Abstract:A series of three-way catalysts was prepared by different cell density substrates with different precious metal contents and washcoat loading. Light-off characteristics of the catalysts were studied by analog computation and tested on engine bench. The results indicate that high cell density of the substrate can improve the catalyst light-off characteristics and air-fuel ratio characteristics markedly, decrease precious metals content in the catalyst and enhance the capability of purifying HCs. The light-off temperature is dependent on the synergic relationship between the substrate cell density and precious metals content. The influence of substrate cell density on air-fuel ratio characteristics is stronger than that of precious metals content. For the aged catalyst, the precious metals content is still an important factor for maintaining catalytic conversion
Keywords:three-way catalyst  substrate  cell structure  light-off characteristic
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