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纳米TiO_2/柞蚕丝素对柞蚕丝绸的整理
引用本文:贾艳梅,黎谦.纳米TiO_2/柞蚕丝素对柞蚕丝绸的整理[J].丝绸,2011,48(10).
作者姓名:贾艳梅  黎谦
作者单位:1. 辽东学院化工与材料学院,辽宁丹东,118000
2. 武汉纺织大学化学工程学院,武汉,430073
基金项目:中国纺织工业协会科技指导性项目(2011043)
摘    要:自制纳米TiO2与柞蚕丝素的混合溶液整理柞蚕丝绸,采用激光粒度仪测定了纳米TiO2溶胶及其柞蚕丝素整理液的粒径,利用红外光谱、X射线衍射和扫描电镜方法对整理前后的柞蚕丝结构进行了表征;对整理前后柞蚕丝绸的紫外线透过率、悬垂风格、白度、撕破强力等指标进行测定。结果表明,制备的TiO2及其柞蚕丝素整理液的平均粒径(D50)分别为1.13 nm和14.2 nm;经纳米TiO2/柞蚕丝素整理后,柞蚕丝纤维表面有新物质固着,表面由光滑变得粗糙,柞蚕丝纤维聚集态结构无明显变化,整理后柞蚕丝绸的抗紫外性能和悬垂风格提高,白度和强力稍有下降。

关 键 词:纳米TiO2  柞蚕丝素  柞蚕丝  结构  性能  

Structure and properties of tussah silk treated with nano-TiO_2 and tussah silk fibroin
JIA Yan-mei,LI Qian.Structure and properties of tussah silk treated with nano-TiO_2 and tussah silk fibroin[J].Silk Monthly,2011,48(10).
Authors:JIA Yan-mei  LI Qian
Affiliation:JIA Yan-mei1,LI Qian2(1.College of Chemical Engineering and Materials,Eastern Liaoning University,Dandong 118000,China,2.College of Chemical Engineering,Wuhan Textile University,Wuhan 430073,China)
Abstract:Tussah silk were treated with self-made nano-TiO2 and tussah silk fibroin mixture,the structure and properties of tussah silk fiber before and after finishing were measured.The sizes of nano-TiO2 and the nano-TiO2/fibroin mixture finishing solution were measured by laser particle analyzer,and the structure of the tussah silk fiber before and after finishing were characterized by the infrared spectroscopy(FT-IR),X-ray diffraction(XRD) and scanning electron microscopy(SEM) methods.Furthermore,the UV resistanc...
Keywords:Nano-TiO2  Tussah silk fibroin  Tussah silk fiber  Structure  Properties  
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