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电场对(Ba0.97Ca0.03)(Ti0.82Zr0.18)O3无铅压电陶瓷铁电性的影响
引用本文:张小龙,王传方,邓湘云,杨仁波,韩立仁,刘佳,杨学良,王依山,邵健,李德军. 电场对(Ba0.97Ca0.03)(Ti0.82Zr0.18)O3无铅压电陶瓷铁电性的影响[J]. 功能材料, 2012, 43(17): 2369-2372
作者姓名:张小龙  王传方  邓湘云  杨仁波  韩立仁  刘佳  杨学良  王依山  邵健  李德军
作者单位:1. 天津师范大学物理与电子信息学院,天津,300387
2. 天津师范大学物理与电子信息学院,天津300387/海南大学材料与化工学院,热带岛屿资源先进材料教育部重点实验室,硅锆钛资源综合开发与利用海南省重点实验室,海南海口570228
基金项目:国家自然科学基金资助项目,国家高技术研究发展计划(863计划)资助项目
摘    要:采用溶胶-凝胶方法制备了(Ba0.97Ca0.03)(Ti0.82Zr0.18)O3无铅压电陶瓷。在电场1~8kV/cm下,频率为0.01~10Hz范围内,对其电滞回线进行了分析。实验结果表明(Ba0.97Ca0.03)(Ti0.82Zr0.18)O3陶瓷的电滞回线随电场值和频率的变化明显,在低电场下,随着频率的增加矫顽场(Ec)单调减小,在低频下剩余极化(Pr)增加;而在高电场下,随着频率的增加Ec单调增大,电滞回线达到饱和时,电滞回线随不同测试频率无明显变化。

关 键 词:溶胶-凝胶  无铅陶瓷  电滞回线  铁电性  电场

Effect of electric field on ferroelectric properties in lead-free(Ba0.97Ca0.03)(Ti0.82Zr0.18)O3 ceramics
ZHANG Xiao-long,WANG Chuan-fang,DENG Xiang-yun,YANG Ren-bo,HAN Li-ren,LIU Jia,YANG Xue-liang,WANG Yi-shan,SHAO Jian,LI De-jun. Effect of electric field on ferroelectric properties in lead-free(Ba0.97Ca0.03)(Ti0.82Zr0.18)O3 ceramics[J]. Journal of Functional Materials, 2012, 43(17): 2369-2372
Authors:ZHANG Xiao-long  WANG Chuan-fang  DENG Xiang-yun  YANG Ren-bo  HAN Li-ren  LIU Jia  YANG Xue-liang  WANG Yi-shan  SHAO Jian  LI De-jun
Affiliation:1(1.College of Physics and Electronic Information,Tianjin Normal University,Tianjin 300387,China; 2.Key Laboratory of Advanced Materials of Tropical Island Resources,Ministry of Education, Hainan Provincial Key Laboratory of Research on Utilization of Si-Zr-Ti Resources, Materials and Chemical Engineering Institute,Hainan University,Haikou 570228,China)
Abstract:The(Ba0.97Ca0.03)(Ti0.82Zr0.18)O3 ceramics were prepared by sol-gel technique.The evolution of the ferroelectric hysteresis loops was analyzed at frequencies ranging from 0.01 to 10Hz and in a field of 1-8kV/cm.The results showed that the electric field and frequency dependence of hysteresis loops were obvious.At low field,coercive field(Ec) decreased monotonically with frequency increasing,and remanent polarization increased at low frequency.But at high field,Ec increased monotonically with frequency increasing,and the evolution of the hysteresis loops is not obvious with different testing frequency when the hysteresis loops become saturated.
Keywords:sol-gel  lead-free ceramics  hysteresis loops  ferroelectricity  electric field
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