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Preparation and characterization of LiAEAlF6:Eu (AE=Mg, Ca, Sr or Ba) phosphors
Authors:PD Belsare  SV Moharil  SK Omanwar  SM Dhopte
Affiliation:a Physics Department, Shri Ramdeobaba K.N. Engineering College, Katol Road, Nagpur 440013, India
b Department of Physics, Nagpur University, Nagpur 440010, India
c Department of Physics, Amaravati University, Amaravati 444602, India
d National Environmental Engineering Research Institute, Nehru Marg, Nagpur, India
Abstract:Wet chemical synthesis of LiAEAlF6:Eu (AE=Mg, Ca, Sr or Ba) phosphors is described. Formation of single-phase compounds LiCaAlF6 and LiSrAlF6 was confirmed by XRD. LiCaAlF6:Eu and LiSrAlF6:Eu phosphors exhibited broadband emission corresponding to intraconfigurational transition 4f65d1→4f7(8S7/2). LiMgAlF6:Eu exhibits a narrow line emission corresponding to 6PJ8S7/2 transition of 4f7 configuration besides the band emission. LiBaAlF6:Eu, on the other hand, was found to yield predominantly line emission.
Keywords:78  55  m  78  55  Hx
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