| 聚丙烯腈/磺化聚苯醚质子交换膜的制备和性能 |
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| 引用本文： | 颜文艳,于爱丽,张秀菊,杨华军,蔡祥,谭绍早. 聚丙烯腈/磺化聚苯醚质子交换膜的制备和性能[J]. 工程塑料应用, 2011, 39(8): 44-47 |
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| 作者姓名： | 颜文艳 于爱丽 张秀菊 杨华军 蔡祥 谭绍早 |
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| 作者单位： | 1. 暨南大学化学系,广州,510632
2. 暨南大学材料科学与工程系,广州,510632 |
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| 基金项目： | 国家自然科学基金项目(20871058,20971028,21006038); 省部(院)产学研项目(2008A010,500005,2010B090301036); 广东省自然科学基金重点项目(10251007002000000); 中央高校基本科研业务费专项资金项目(21610102) |
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| 摘 要： | 采用溶液共混浇铸法制备了一系列的聚丙烯腈/磺化聚苯醚(PAN/SPPO)共混质子交换膜.结果表明,磺酸基团成功引入交换膜,共混膜有较好的相容性,没产生相分离,PAN/SPPO共混膜的吸水率和溶胀率明显降低,其热性能稳定.与纯SPPO膜相比,虽然英质子传导率有所下降,但都在10-2～ 10-3S/cm数量级范围内,究全可...
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| 关 键 词： | 聚苯醚 磺化 质子交换膜 燃麟电池 |
PREPARATION AND PROPERTIES OF POLYACRYLONITRILE/SULFONATED POLY(PHENYLENE OXIDE) PROTON CONDUCTIVE MEMBRANES |
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| Yan Wenyan,Yu Aili,Zhang Xiuju,Yang Huajun,Cai Xiang,Tan Shaozao. PREPARATION AND PROPERTIES OF POLYACRYLONITRILE/SULFONATED POLY(PHENYLENE OXIDE) PROTON CONDUCTIVE MEMBRANES[J]. Engineering Plastics Application, 2011, 39(8): 44-47 |
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| Authors: | Yan Wenyan Yu Aili Zhang Xiuju Yang Huajun Cai Xiang Tan Shaozao |
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| Affiliation: | Yan Wenyan1,Yu Aili1,Zhang Xiuju2,Yang Huajun2,Cai Xiang1,Tan Shaozao1(1.Department of Chemistry,Jinan University,Guangzhou510632,China,2.Department of Aterial Science and Engineering,China) |
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| Abstract: | A series of polyacrylonitrile/sulfonated poly(phenylene oxide)(PAN/SPPO)proton membranes was prepared by solution blending.The Fourier transform infrared spectrometer of SPPO indicated the introduce of sulfonic acid group.Scanning electron microscopy showed that the blend membrane had good compatibility,no phase separation.The physical and chemical properties of the membrane showed that PAN/SPPO blend membrane water absorption and swelling rate was significantly reduced,and its thermal stability was good.Co... |
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| Keywords: | poly(phenylene oxide) sulfonation proton exchange membrane fuel cells |
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