Characteristics of a continuous Si-Ti-C-O fibre with low oxygen content using an organometallic polymer precursor |
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Authors: | Masaki Shibuya Takemi Yamamura |
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Affiliation: | (1) Ube Research Laboratory, Corporate Research and Development, Ube Industries, Ltd., 1978-5 Kogushi, Ube-city, 755 Yamaguchi-ken, Japan |
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Abstract: | A continuous Si-Ti-C-O fibre with 12 wt% oxygen content, which is lower than the usual 18 wt% found in the normal fibres, was synthesized by using polytitanocarbosilane which has fewer Si-Si bonds than the usual precursor polymer. The density, tensile strength, tensile modulus and thermal conductivity were found to be 2.37 g cm–3, 3.4±0.3 GPa, 190±10 GPa and 1.40 W m–1 K–1, respectively. Amongst these properties, the tensile modulus was improved by 20 GPa and the thermal conductivity had a higher value in comparison with that of the ordinary Si-Ti-C-O fibre with 18 wt% oxygen content. The Si-Ti-C-O fibre with a 12 wt% oxygen content has a better heat resistance above 1400 °C in an argon atmosphere and 1300 °C in air, than the usual fibre. About 60 and 40% of its tensile strength at room temperature were retained in air at respectively, 1500 and 1600 °C. This improved ceramic fibre is considered to be useful as a reinforcing material for advanced composites such as high-temperature ceramic matrix composites and metal matrix composites. |
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