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电化学辅助一步法浸锌工艺的初步研究
引用本文:吴惠民,周海晖,吴显平,黄鹏程,旷亚非.电化学辅助一步法浸锌工艺的初步研究[J].电镀与涂饰,2009,28(9).
作者姓名:吴惠民  周海晖  吴显平  黄鹏程  旷亚非
作者单位:湖南大学化学化工学院,湖南,长沙,410082
摘    要:研制了一种一步法浸锌工艺.采用电化学辅助的方法改变铝在浸锌液中的界面电位并加速铝表面氧化膜的活化,以获得均匀致密的浸锌层.研究了电流密度、时间、温度、搅拌等工艺参数对3003铝合金上铜镀层结合力的影响.该浸锌液的工作温度为0~15 ℃.当控制通过试样的阳极电流密度为0.6~1.5 A/dm2,浸锌时间30~60 s时,在静止或搅拌的情况下都能获得结合力较佳的铜镀层.该方法无需硝酸浸蚀步骤,可一步完成铝及其合金的浸锌处理,有着良好的应用前景.

关 键 词:铝合金  浸锌  电化学  镀铜  结合力

Preliminary study on one-step zinc dipping process with electrochemical assistance
WU Hui-min,ZHOU Hai-hui,WU Xian-ping,HUANG Peng-cheng,KUANG Ya-fei.Preliminary study on one-step zinc dipping process with electrochemical assistance[J].Electroplating & Finishing,2009,28(9).
Authors:WU Hui-min  ZHOU Hai-hui  WU Xian-ping  HUANG Peng-cheng  KUANG Ya-fei
Affiliation:WU Hui-min,ZHOU Hai-hui,WU Xian-ping,HUANG Peng-cheng,KUANG Ya-fei College of Chemistry , Chemical Engineering,Changsha 410082,China
Abstract:A one-step zinc dipping process was developed. The interfacial potential of aluminum in zinc dipping solution was changed by electrochemical assistance method, which can also accelerate the activating speed of oxide film on aluminum surface and hence uniform and compact zinc-dipping film can be obtained. The effects of current density, dipping time, temperature and agitation on the adhesion of copper electrodeposit on 3003 aluminum alloy were studied. The effective temperature range of zinc dipping process ...
Keywords:aluminum alloy  zinc dipping  electrochemistry  copper electroplating  adhesion strength  
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