| 有机硅高沸物裂解歧化制备二甲基二氯硅烷的研究进展 |
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| 引用本文： | 赵建波,张宁. 有机硅高沸物裂解歧化制备二甲基二氯硅烷的研究进展[J]. 工业催化, 2003, 11(11): 37-41 |
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| 作者姓名： | 赵建波 张宁 |
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| 作者单位： | 南昌大学应用化学研究所， 江西 南昌 330047 |
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| 基金项目： | 江西省教委重大科技攻关项目 |
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| 摘 要： | 在直接法合成甲基氯硅烷单体过程中，除目标产物二甲基二氯硅烷外，还产生了大量的高沸物。本文介绍了催化裂解歧化有机硅高沸物制备二甲基二氯硅烷的研究进展。
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| 关 键 词： | 有机硅高沸物 二甲基二氯硅烷 裂解歧化 |
| 文章编号： | 1008-1143(2003)11-0037-05 |
| 修稿时间： | 2003-07-18 |
Catalytic conversion of high-boiling components in silicone to dimethyldichlorosilane |
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| ZHAO Jian-bo,ZHANG Ning. Catalytic conversion of high-boiling components in silicone to dimethyldichlorosilane[J]. Industrial Catalysis, 2003, 11(11): 37-41 |
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| Authors: | ZHAO Jian-bo ZHANG Ning |
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| Affiliation: | Institute of Applied Chemistry, Nanchang University, Jiangxi Nanchang 330047,China |
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| Abstract: | During the preparation of methylchlorosilane via direct synthesis (Muller-Rochow method), large quantity of high-boiling components form as byproduct along with the target compound-dimethyldichlorosilane. Advances in the catalytic conversion of the high-boiling component in silicone to dimethyldichlorosilane by splitting decomposition and disproportionation were reviewed. |
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| Keywords: | high-boiling component silicone dimethyldichlorosilane catalytic splitting disproportionation decomposition |
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