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H2S对低碳钢在焦炉煤气中腐蚀行为的影响
引用本文:黄旭,陈杰.H2S对低碳钢在焦炉煤气中腐蚀行为的影响[J].钢铁钒钛,1998,19(4):14-20.
作者姓名:黄旭  陈杰
作者单位:攀枝花钢铁研究院
摘    要:研究了H2S对低碳钢在焦炉煤气中腐蚀动力学的影响,证实在H2S含量为0.15g/m^3时电极过程的控制步骤出现明显的转化,「H2S」〈0.15g/m^3为阴极过程控制,「H2S」〉0.15g/m^3为阳极过程控制,用直接证据证明在高H2S含量的煤气中低碳钢能够在表面形成和密的保护膜,并且从理论上解释了这些现象。

关 键 词:低碳钢  焦炉煤气  腐蚀  硫化氢

EFFECT OF H_2S ON CORROSION BEHAVIOR OF LOW CARBON STEEL IN COKE OVEN GAS
Huang Xu, Cheng Jie, Yao Yongguo, Deng Jun, He Qipin, Let Xinhua.EFFECT OF H_2S ON CORROSION BEHAVIOR OF LOW CARBON STEEL IN COKE OVEN GAS[J].Iron Steel Vanadium Titanium,1998,19(4):14-20.
Authors:Huang Xu  Cheng Jie  Yao Yongguo  Deng Jun  He Qipin  Let Xinhua
Affiliation:Panzhihua Iron & Steel Research Institute
Abstract:The effect of H2S on the corrosion dynamics of low carbon steel in coke oven gas was investigated. It is showed that the electropolar process controlling step changes remarkably at 0.15g/m3 H2S,corrosion controlling step is cathodic reactions at<0.15g/m3 H2S and anodic reactions at>0.15g/m3H2S.There is evidence that the dense protective film forms on the surface of low carbon steel in high H2S coke oven gas. The phenomena are theoretically explained.
Keywords:low carbon steel  coke oven gas  corrosion  H2S  
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