| NaA分子筛膜蒸汽渗透促进丙烯酸/乙醇的酯化反应 |
| |
| 引用本文： | 李小强,张小明,索继栓. NaA分子筛膜蒸汽渗透促进丙烯酸/乙醇的酯化反应[J]. 应用化学, 2012, 29(8): 974-976. DOI: 10.3724/SP.J.1095.2012.00369 |
| |
| 作者姓名： | 李小强 张小明 索继栓 |
| |
| 作者单位： | (中国科学院成都有机化学研究所 成都 610041) |
| |
| 基金项目： | 中国科学院“西部之光”人才培养计划 |
| |
| 摘 要： | 以对甲苯磺酸为催化剂，利用亲水性NaA分子筛膜蒸汽渗透过程，选择性地将丙烯酸和乙醇酯化反应产物中的水原位分离出反应器，打破反应平衡限制，使反应不断向右进行，反应15 h丙烯酸转化率达到100%。
|
| 关 键 词： | 对甲苯磺酸 NaA分子筛膜 蒸汽渗透 丙烯酸乙酯 |
| 收稿时间： | 2011-08-24 |
| 修稿时间： | 2011-10-31 |
Vapor Permeation Aided Esterification of Ethanol/Acrylic Acid Using NaA Zeolite Membrane |
| |
| LI Xiaoqiang,ZHANG Xiaoming,SUO Jishuan. Vapor Permeation Aided Esterification of Ethanol/Acrylic Acid Using NaA Zeolite Membrane[J]. Chinese Journal of Applied Chemistry, 2012, 29(8): 974-976. DOI: 10.3724/SP.J.1095.2012.00369 |
| |
| Authors: | LI Xiaoqiang ZHANG Xiaoming SUO Jishuan |
| |
| Affiliation: | (Chengdu Institute of Organic Chemistry,Chinese Academy of Sciences,Chengdu 610041,China) |
| |
| Abstract: | Taking advantage of the hydrophilicity of zeolite A membrane,it was used as a vapor permeation membrane to remove the water generated from the esterification between acrylic acid and ethanol with the presence of p-toluene sulphonic acid as catalyst.This allowed to efficiently separate in situ formed water from the reactor,shift the esterification toward right side and hence substantially enhance the conversion of acrylic acid.Up to 100% conversion could be achieved within 15 h. |
| |
| Keywords: | p-toluene sulfonic acid NaA zeolite membrane vapor permeation ethyl acrylate |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《应用化学》浏览原始摘要信息 |
|
点击此处可从《应用化学》下载全文 |
