| 阿维菌素荧光衍生反应影响因子的研究 |
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| 引用本文： | 谢显传,张少华,王冬生,皇甫伟国,杨挺,何新华.阿维菌素荧光衍生反应影响因子的研究[J].分析化学,2006,34(12):1745-1748. |
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| 作者姓名： | 谢显传 张少华 王冬生 皇甫伟国 杨挺 何新华 |
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| 作者单位： | 南京大学环境学院,南京,210093;上海市农业科学学院植物保护研究所,上海市设施园艺技术重点实验室,上海,201106;宁波市农业科学研究所农产品检测中心,宁波,315040;宁波市产品质量监督检验所,宁波,315040;上海市农业科学学院植物保护研究所,上海市设施园艺技术重点实验室,上海,201106;宁波市农业科学研究所农产品检测中心,宁波,315040 |
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| 基金项目： | 上海市科技兴农重点攻关项目资助(沪农科攻字2003No.10-6) |
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| 摘 要： | 论文研究与探讨了不同温度(-20℃、0℃、20℃、40℃、60℃)、光照(0 Lux,123.8 Lux,1665.5 Lux,1108.2 Lux)、反应时间(1~720 m in)、衍生试剂浓度等因子对阿维菌素荧光衍生反应的影响。研究结果表明,环境温度对衍生反应影响不显著;衍生反应对太阳光线敏感,其机理是阿维菌素衍生产物易快速发生光解;高浓度的衍生试剂对反应表现一定抑制作用;衍生反应在30 m in左右达到峰值,其产物在室温、避光条件下8 h内保持稳定。
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| 关 键 词： | 阿维菌素 荧光 高效液相色谱 衍生反应 |
| 收稿时间： | 09 15 2005 12:00AM |
| 修稿时间： | 2005-09-152005-12-02 |
Impact factors of Fluorescence Derivatization Reaction of Abamectin |
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| Xie Xianchuan,Zhang Shaohua,Wan Dongshen,Huangpu Weiguo,Yang Ting,He Xinhua.Impact factors of Fluorescence Derivatization Reaction of Abamectin[J].Chinese Journal of Analytical Chemistry,2006,34(12):1745-1748. |
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| Authors: | Xie Xianchuan Zhang Shaohua Wan Dongshen Huangpu Weiguo Yang Ting He Xinhua |
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| Affiliation: | School of the Environment, Nanfing University, Nanjing 210093 ; Plant Protection Research Institute, Shanghai Academy of Agricultural Science, Shanghai Key Laboratory of Protected Horticultural Technology, Shanghai 201106; Analytical Center of Agricultural Produce Ningbo Academy of Agricultural Science, Ningbo 315040; Ningbo Superuvision and Inspection Institute for Product Quality. Ningbo 315040 |
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| Abstract: | The impact factors including temperature,light tehsity,react time et al,of fluorescence derivatization reaction of abamectin were studied.The results show that temperature does not have a significant impact on derivatization reaction;the derivatives are rapid degraded in sun light;the derivatization reaction is inhibited when the derivatization reagent is at high concentration;the reaction to produce the fluorescent derivatives is finished in 30 min,and the derivatives are stable for about 8 h at normal temperature and lightless. |
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| Keywords: | Abamectin fluorescence high performance liquid chromatography derivatization |
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