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邻苯二甲酸Pb(Ⅱ)配合物纳米颗粒的合成及其燃烧催化性能研究
引用本文:洪伟良,赵凤起,刘剑洪,田德余,罗仲宽,陈 沛,罗 阳.邻苯二甲酸Pb(Ⅱ)配合物纳米颗粒的合成及其燃烧催化性能研究[J].无机化学学报,2004,20(8):996-1000.
作者姓名:洪伟良  赵凤起  刘剑洪  田德余  罗仲宽  陈 沛  罗 阳
作者单位:1. 深圳大学师范学院化生系,深圳,518060
2. 西安近代化学研究所,西安,710065
基金项目:国防科技重点实验室基金资助项目(No.51455030303QT5101)。
摘    要:The nanoparticle Pb(Ⅱ)-Phtalate complex was synthesized by liquid dispersion deposition method using Pb(Ac)2·3H2O and potassium acid phthalate as the reactant. The nanoparticle complexes were characterized with TEM, XRD, TG, DSC and IR. The composition of the nanoparticle PbPht complex was determined by chemical and elemental analysis. The catalytic performance of nanoparticle complex on the combustion of RDX-CMDB propellant was investigated. The results showed the average particle size of complex were about 50 nm. The nanoparticle Pb(Ⅱ)-Phtalate complex can enhance burning-rate of propellant by 135%, and lower the pressure exponent by 74%.

关 键 词:纳米粒子    邻苯二甲酸  分散沉淀法  配合物  燃烧催化剂

Synthesis and Combustion Catalytic Activity of Nanoparticle Pb(Ⅱ)-Phtalate Complex
HONG Wei-Liang,ZHAO Feng-Qi,LIU Jian-Hong,TIAN De-Yu,LUO Zhong-Kuan,CHEN Pei and LUO Yang.Synthesis and Combustion Catalytic Activity of Nanoparticle Pb(Ⅱ)-Phtalate Complex[J].Chinese Journal of Inorganic Chemistry,2004,20(8):996-1000.
Authors:HONG Wei-Liang  ZHAO Feng-Qi  LIU Jian-Hong  TIAN De-Yu  LUO Zhong-Kuan  CHEN Pei and LUO Yang
Abstract:
Keywords:nanoparticle  lead  phthalic acid  dispersion deposition method  complex  combustion catalyst
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