| 降冰片烯及其衍生物开环易位聚合的研究进展 |
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| 引用本文： | 张丹枫. 降冰片烯及其衍生物开环易位聚合的研究进展[J]. 高分子材料科学与工程, 2000, 16(1): 13-15 |
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| 作者姓名： | 张丹枫 |
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| 作者单位： | 上海白猫有限公司,上海,200231 |
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| 摘 要： | 综述了降冰片烯及其衍生物开环易位聚合的研究进展。分析了ＲＯＭＰ反应特点，催化剂类型对于ＮＥＢ衍生物的ＲＯＭＰ；由于聚合反应发生成ＮＢＥ环上，其衍生物上的取代基赋予了该聚合物特殊的功能，为合成大分子单体提供了一种新方法。还报道了ＮＢＥ的活性聚合研究。
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| 关 键 词： | 降冰片烯 衍生物 开环聚合 |
| 文章编号： | 1000-7555(2000)01-0013-03 |
| 修稿时间： | 1998-01-13 |
ADVANCES IN THE STUDY ON RING-OPENING METATHESIS POLYMERIZATION OF NORBORNENE AND ITS DERIVATIVES |
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| ZHANG Dan-feng. ADVANCES IN THE STUDY ON RING-OPENING METATHESIS POLYMERIZATION OF NORBORNENE AND ITS DERIVATIVES[J]. Polymer Materials Science & Engineering, 2000, 16(1): 13-15 |
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| Authors: | ZHANG Dan-feng |
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| Abstract: | The development of study on ring opening metathesis polymerization(ROMP) of norbornene(NBE) and its derivativesis reviewed with 30 references. The unique feature of this kind of polymerization is that the unsaturated carbon carbon double bonds and rings structure are remained in the polymer. W, Mo,Re, Ru, Ti, etc. halides and their organometallics are effective catalysts for NBE polymerization. The functional polymers can be obtained by ROMP of NBE derivatives, which are substituted by ester, fluoride, borane, silicane, etc. Some of these can be transformed into a variety of functionalities. The studies of living polymerization of NBE were also introduced. |
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| Keywords: | ring opening metathesis polymerization norbornene and its derivatives |
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