A Highly Selective Fluorescent Chemosensor for Cu2+ |
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Authors: | GUAN Jie ZHANG Peng WEI Taibao LIN Qi YAO Hong ZHANG Youming |
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Affiliation: | Key Laboratory of Eco-environment-related Polymer Materials, Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, P. R. China |
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Abstract: | A new Zn2+ probe L2-Zn(L2=naphthofuran carbonylhydrazone derivant) was synthesized as a fluorescence chemosensor for Cu2+, by which Cu2+ ion could be detected with high selectivity and sensitivity in a wide pH range via a displacement “turn-off” signaling strategy. Whereas the coordination between Zn2+ and L2 resulted in a considerable enhancement of typical luminescence of a naphthalofuran group in complex L2-Zn, the addition of Cu2+ ion led to a dramatic decrease in the emission intensity of probe L2-Zn at about 503 nm(excitation at 423 nm). The competitive fluorescent experiments showed that other metal ions, such as Hg2+, Fe3+, Ag+, Ca2+, Co2+, Ni2+, Cd2+, Pb2+, Zn2+, Cr3+ and Mg2+ could not impact the detection of Cu2+. The detection limit of the novel probe L2-Zn for Cu2+ ion was as low as 2.3×10-7 mol/L, which is far lower than the guideline value of 1.6×10-5 mol/L of the United States Environmental Protection Agency. |
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Keywords: | Znic complex Fluorescent switch Copper ion Turn-off signal |
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