Effects of blend composition and dynamic vulcanization on the morphology and dynamic viscoelastic properties of PP/EPDM blends |
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Authors: | E.V. Prut N.A. Erina J. Karger-Kocsis T.I. Medintseva |
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Affiliation: | 1. Semenov Institute of Chemical Physics of Russian Academy of Sciences, Moscow 119991, Russia;2. Veeco Instruments Inc., Santa Barbara, California 93117;3. Institut für Verbundwerkstoffe GmbH (Institute for Composite Materials), Kaiserslautern University of Technology, D-67653 Kaiserslautern, Germany |
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Abstract: | The morphology and dynamic viscoelastic properties of isotactic polypropylene (PP) blended with oil-free/oil-extended ethylene–propylene–diene (EPDM) rubbers were studied. Unvulcanized and dynamically vulcanized blends with the compositions PP/EPDM = 50/50 and = 30/70 were investigated. The morphology was observed by phase contrasted atomic force microscopy. The dynamic viscoelastic properties were determined with a rheometer of plate–plate configuration. It was shown that the rheological behavior was strongly affected by both the composition and the morphology of the blends. Significant improvement in the flowability of the dynamically vulcanized blends was observed when oil-extended EPDM was used instead of the oil-free version. It was demonstrated that the rheological properties are mostly controlled by the elastomer phase at low frequencies, while in the high-frequency range the influence of PP becomes dominant. The peculiarities in the rheological behavior of the thermoplastic elastomers (uncured blends, TPE) and thermoplastic dynamic vulcanizates (TPV, dynamically cured blends) containing oil-extended EPDMs were traced to a limited compatibility between the PP and EPDM components in the melt. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 |
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Keywords: | ethylene–propylene–diene rubber poly(propylene) rheology thermoplastic elastomer dynamic vulcanization morphology |
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