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| 4-(氮杂-15-冠-5)-1,8-萘酰亚胺荧光探针的合成及性能研究 | |
| 引用本文： | 郭祥峰,朱宝存,刘媛媛,张宇,贾丽华,钱旭红.4-(氮杂-15-冠-5)-1,8-萘酰亚胺荧光探针的合成及性能研究[J].有机化学,2006,26(4):504-507. |
| 作者姓名： | 郭祥峰 朱宝存 刘媛媛 张宇 贾丽华 钱旭红 |
| 作者单位： | 1. 齐齐哈尔大学化学与化工学院,齐齐哈尔,161006 2. 齐齐哈尔大学化学与化工学院,齐齐哈尔,161006;大连理工大学精细化工国家重点实验室,大连,116012 3. 大连理工大学精细化工国家重点实验室,大连,116012 |
| 基金项目： | 教育部(No.地方205040)资助项目 |
| 摘 要： | N-丁基-4-溴-1,8-萘酰亚胺与二乙醇胺反应, 合成了N-丁基-4-二(2-羟乙基)氨-1,8-萘酰亚胺, 进一步与对甲基苯磺酸二缩三乙二醇双酯反应合成了N-丁基-4-(氮杂-15-冠-5)-1,8-萘酰亚胺. 用NMR, IR, MS等表征了产物结构. 该化合物在二氯甲烷溶液中识别Li＋和Na＋, 识别后吸收光谱和荧光光谱蓝移. |
| 关 键 词： | 氮杂冠醚 萘酰亚胺 荧光探针 合成 |
| 收稿时间： | 05 24 2005 12:00AM |
| 修稿时间： | 09 29 2005 12:00AM |
Synthesis and Properties of N-Butyl-4-(aza-15-crown-5)-1,8-naphthalimide as a Fluorescent Probe |
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| GUO,Xiang-Feng,ZHU,Bao-Cun,LIU,Yuan-Yuan,ZHANG,Yu,JIA,Li-Hua,QIAN,Xu-Hong.Synthesis and Properties of N-Butyl-4-(aza-15-crown-5)-1,8-naphthalimide as a Fluorescent Probe[J].Chinese Journal of Organic Chemistry,2006,26(4):504-507. | |
| Authors: | GUO Xiang-Feng ZHU Bao-Cun LIU Yuan-Yuan ZHANG Yu JIA Li-Hua QIAN Xu-Hong |
| Affiliation: | 1. College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006;2. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 |
| Abstract: | N-Butyl-4-(aza-15-crown-5)-1,8-naphthalimide (BACN) was synthesized through the reaction of 3,6-dioxa-1,8-octylene bis-p-tosylate with N-butyl-4-bis(2-hydroxyethyl)amino-1,8-naphthalimide prepared from diethanolamine and N-butyl-4-bromo-1,8-naphthalimide. The compounds were characterized by NMR, IR and MS spectra, and BACN can recognize Li and Na in dichloromethane with blue-shift of the absorp- tion and fluorescence spectra. |
| Keywords: | aza-15-crown-5 naphthalimide fluorescent probe synthesis |
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