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| 超分子自组装合成杯[4]芳烃黄原酸镍(Ⅱ)配合物 | |
| 引用本文： | 杨发福,陈希磊,蔡秀琴,林 深,陈远荫.超分子自组装合成杯[4]芳烃黄原酸镍(Ⅱ)配合物[J].无机化学学报,2004,20(9):1081-1084. |
| 作者姓名： | 杨发福 陈希磊 蔡秀琴 林 深 陈远荫 |
| 作者单位： | 1. 福建师范大学化学与材料学院,福州,350007;福建物质结构研究所结构化学国家重点实验室,福州,350007 2. 福建师范大学化学与材料学院,福州,350007 3. 武汉大学化学系,武汉,430072 |
| 基金项目： | 福建省自然科学基金(No.E0220002)，福建物构所结构化学国家重点实验室开放基金(No.030071)资助项目。 |
| 摘 要： | 利用二维和三维的大环及笼状主体分子与金属离子直接进行自组装反应合成新型有机无机杂化分子是当前超分子领域的研究热点之一。这类分子不仅具有新奇的光、电、磁等特性，而且还可作为新型的主体分子在客体识别、催化、吸附与分离等方面有广阔的应用前景。杯芳烃是有机超分子领域广受 |
| 关 键 词： | 杯[4]芳烃 黄原酸盐 自组装 镍配合物 |
| 修稿时间： | 2004年3月2日 |
Supramolecular Self-assembled Calix[4]arene Xanthate-Ni2+ Complex Compound |
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| YANG Fa-Fu,CHEN Xi-Lei,CAI Xiu-Qin,LIN Shen and CHEN Yuan-Yin.Supramolecular Self-assembled Calix[4]arene Xanthate-Ni2+ Complex Compound[J].Chinese Journal of Inorganic Chemistry,2004,20(9):1081-1084. | |
| Authors: | YANG Fa-Fu CHEN Xi-Lei CAI Xiu-Qin LIN Shen and CHEN Yuan-Yin |
| Affiliation: | College of Chemistry & material sience , Fujian Normal University, Fuzhou 350007;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002,College of Chemistry & material sience , Fujian Normal University, Fuzhou 350007,College of Chemistry & material sience , Fujian Normal University, Fuzhou 350007,College of Chemistry & material sience , Fujian Normal University, Fuzhou 350007;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002 and Department of Chemistry, Wuhan University, Wuhan 430072 |
| Abstract: | Under the action of CS2 and KOH in dioxane solution, calix4]arene derivative 2 was converted into calix4]arene derivative containing xanthate salt (3) and its Ni2+ complex compound 4 was prepared by self-assembled reaction with NiSO4 further. The structures of new compounds were confirmed by elemental analyses, IR, UV, 1H NMR, MS techniques. The Ni2+ of complex compound 4 was in high-spin state by its ESR spectrum. |
| Keywords: | calix[4]arene xanthate self-assembled Ni2+ complex |
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