| Hydrothermal Synthesis, Crystal Structure and Electrochemical Properties of Complex Mn2（phen）2（p-CBA）4（H2O） |
| |
| 引用本文： | 李薇,李昶红,杨颖群,匡云飞.Hydrothermal Synthesis, Crystal Structure and Electrochemical Properties of Complex Mn2（phen）2（p-CBA）4（H2O）[J].结构化学,2007,26(9):1057-1060. |
| |
| 作者姓名： | 李薇 李昶红 杨颖群 匡云飞 |
| |
| 作者单位： | Department of Chemistry and Materials Science Hengyang Normal University，Department of Chemical Engineering Hunan Institute of Technology，Department of Chemistry and Materials Science Hengyang Normal University，Department of Chemistry and Materials Science Hengyang Normal University，Hengyang 421008 China，Hengyang 421002 China，Hengyang 421008 China，Hengyang 421008 China |
| |
| 基金项目： | 湖南省教育厅资助项目
,
the Research Award Fund for Outstanding Young Teachers of Hengyang Normal University
,
the Construct Program of the Key Discipline in Hunan Province |
| |
| 摘 要： | One novel complex Mn2(phen)2(p-CBA)4(H2O) has been hydrothermally syn- thesized from p-chlorobenzoic acid (p-CBA), 1,10-phenanthroline (phen) and anhydrous man- ganese(Ⅱ) sulfate and then characterized. Crystal data for this complex: monoclinic, space group C2/c, with a = 2.3416(3), b = 1.5604(2), c =1.5605(2) nm, β = 121.048(2)o, V = 4.8849(12) nm3, Dc = 1.510 g/cm3, Mr = 555.26, Z = 8, μ = 0.798 mm-1, F(000) = 2256, GOOF = 1.032, the final R = 0.0393 and wR = 0.0816. The crystal structure shows that two neighboring manganese(Ⅱ ) ions are linked together by two bridge-chelating p-chlorobenzoic groups and one bridging water molecule, forming a cage structure with the Mn–Mn bond distance of 0.3512 nm. Each manganese(Ⅱ ) ion is coordinated by two nitrogen atoms of one 1,10-phenanthroline molecule and four oxygen atoms from three p-chlorobenzoic acid anions and one water molecule, giving a distorted octahedral coordination geometry. The cyclic voltammetric behavior of the complex was also investigated.
|
| 关 键 词： | manganese( Ⅱ ) complex crystal structure electrochemical property |
| 收稿时间： | 2006-12-27 |
| 修稿时间： | 2007-03-14 |
Hydrothermal Synthesis, Crystal Structure and Electrochemical Properties of Complex Mn2(phen)2(p-CBA)4(H2O) |
| |
| LI Wei,LI Chang-Hong,YANG Ying-Qun,KUANG Yun-Fei.Hydrothermal Synthesis, Crystal Structure and Electrochemical Properties of Complex Mn2(phen)2(p-CBA)4(H2O)[J].Chinese Journal of Structural Chemistry,2007,26(9):1057-1060. |
| |
| Authors: | LI Wei LI Chang-Hong YANG Ying-Qun KUANG Yun-Fei |
| |
| Abstract: | One novel complex Mn2(phen)2(p-CBA)4(H2O) has been hydrothermally synthesized from p-chlorobenzoic acid (p-CBA), 1,10-phenanthroline (phen) and anhydrous man-ganese(Ⅱ) sulfate and then characterized. Crystal data for this complex: monoclinic, space group C2/c, with a = 2.3416(3), b = 1.5604(2), c =1.5605(2) nm, β = 121.048(2)° , V= 4.8849(12) nm3, Dc = 1.510 g/cm3, Mr = 555.26, Z = 8, μ = 0.798 mm-1, F(000) = 2256, GOOF = 1.032, the final R = 0.0393 and wR = 0.0816. The crystal structure shows that two neighboring manganese(Ⅱ) ions are linked together by two bridge-chelating p-chlorobenzoic groups and one bridging water molecule, forming a cage structure with the Mn-Mn bond distance of 0.3512 nm. Each manganese(Ⅱ) ion is coordinated by two nitrogen atoms of one 1,10-phenanthroline molecule and four oxygen atoms from three p-chlorobenzoic acid anions and one water molecule, giving a distorted octahedral coordination geometry. The cyclic voltammetric behavior of the complex was also investigated. |
| |
| Keywords: | manganese(Ⅱ) complex crystal structure electrochemical property Synthesis Hydrothermal Complex Electrochemical Properties Structure Crystal cyclic voltammetric behavior coordination geometry four oxygen anions nitrogen atoms forming cage crystal structure bond distance |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
