| 由3-二茂铁-2-丁烯酸根和1,10-邻菲啰啉构筑的一维链状铅(II)配位聚合物的合成、晶体结构及电化学性质 |
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| 引用本文： | 李纲,李子峰,吴静霞,王利鹏,侯红卫.由3-二茂铁-2-丁烯酸根和1,10-邻菲啰啉构筑的一维链状铅(II)配位聚合物的合成、晶体结构及电化学性质[J].化学学报,2007,65(14):1363-1367. |
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| 作者姓名： | 李纲 李子峰 吴静霞 王利鹏 侯红卫 |
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| 作者单位： | (郑州大学化学系 郑州 450052) |
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| 基金项目： | 国家自然科学基金
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教育部科学技术研究重点项目 |
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| 摘 要： | Pb(OAc)2•3H2O, 3-二茂铁-2-丁烯酸钠以及1,10-邻菲啰啉在甲醇中反应得到了铅的配位聚合物: Pb(m-OOCCH＝C(CH3)Fc)(m2-OOCCH＝C(CH3)Fc)(phen)]n (Fc＝(h5-C5H5)Fe(h5-C5H4); phen＝1,10-邻菲啰啉). 单晶测试表明: 每个铅离子为六配位, 其中4个氧原子来自4个3-二茂铁-2-丁烯酸根, 另2个氮原子来自邻菲啰啉; 相邻的铅离子通过3-二茂铁-2-丁烯酸根的单齿和双齿氧原子桥连形成了一个无限的一维长链. 研究了标题化合物在DMF溶液中的电化学性能.
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| 关 键 词： | 配位聚合物 铅 3-二茂铁-2-丁烯酸钠 1 10-邻菲啰啉 晶体结构 电化学性质 |
| 收稿时间： | 2006-12-7 |
| 修稿时间： | 2006-12-072007-03-22 |
Synthesis, Crystal Structure and Electrochemical Property of a One- dimensional Chain Pb(II) Coordination Polymer Constructed from 3-Ferrocenylcrotonic Anion and 1,10-Phenanthroline |
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| LI Gang,LI Zi-Feng,WU Jing-Xia,WANG Li-Peng,HOU Hong-Wei.Synthesis, Crystal Structure and Electrochemical Property of a One- dimensional Chain Pb(II) Coordination Polymer Constructed from 3-Ferrocenylcrotonic Anion and 1,10-Phenanthroline[J].Acta Chimica Sinica,2007,65(14):1363-1367. |
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| Authors: | LI Gang LI Zi-Feng WU Jing-Xia WANG Li-Peng HOU Hong-Wei |
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| Affiliation: | (Department of Chemistry, Zhengzhou University, Zhengzhou 450052) |
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| Abstract: | A novel coordination polymer Pb(m-OOCCH＝C(CH3)Fc)(m2-OOCCH＝C(CH3)Fc)(phen)]n (Fc＝(h5-C5H5)Fe(h5-C5H4); phen＝1,10-phenanthroline) was obtained by the reaction of Pb(OAc)2•3H2O with NaOOCCH＝C(CH3)Fc and phen in methanol solution. X-ray structural analysis reveals that each Pb(II) ion in the compound is in a six-coordinated geometry in which four oxygen atoms come from four Fc(CH3)C＝CHCOO－ units, and two nitrogen atoms from the phen ligand. In its solid-state structure, Fc(CH3)C＝CHCOO－ anion acts as m-mode or m2-mode bridging the central Pb(II) ions and thus forming a 1-D chain. The cyclic voltammetries of the title compound and the corresponding ferrocenyl ligand were investigated in DMF solution. |
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| Keywords: | coordination polymer lead(II) sodium 3-ferrocenylcrotonate 1 10-phenanthroline crystal structure electrochemical property |
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