| 一种超亲水自清洁、智能控温的钨掺杂二氧化钒薄膜的制备及其性能表征 |
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| 引用本文： | 孙俊梅,梁子辉,赵丽,董兵海,王世敏.一种超亲水自清洁、智能控温的钨掺杂二氧化钒薄膜的制备及其性能表征[J].材料导报,2018,32(Z2):134-139, 146. |
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| 作者姓名： | 孙俊梅 梁子辉 赵丽 董兵海 王世敏 |
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| 作者单位： | 成都大学药学与生物工程学院,成都 610106,湖北大学有机化工新材料湖北省协同创新中心,武汉 430062;湖北大学功能材料绿色制备与应用教育部重点实验室,武汉 430062;湖北大学高分子材料湖北省重点实验室,武汉 430062,湖北大学有机化工新材料湖北省协同创新中心,武汉 430062;湖北大学功能材料绿色制备与应用教育部重点实验室,武汉 430062;湖北大学高分子材料湖北省重点实验室,武汉 430062,湖北大学有机化工新材料湖北省协同创新中心,武汉 430062;湖北大学功能材料绿色制备与应用教育部重点实验室,武汉 430062;湖北大学高分子材料湖北省重点实验室,武汉 430062,湖北大学有机化工新材料湖北省协同创新中心,武汉 430062;湖北大学功能材料绿色制备与应用教育部重点实验室,武汉 430062;湖北大学高分子材料湖北省重点实验室,武汉 430062 |
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| 基金项目： | 基金项目:国家自然科学基金(21402045)；国家自然科学基金面上项目(51572072)；湖北省教育委员会资助项目(020120103) |
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| 摘 要： | 本实验采用一种简单、低成本有效的溶胶-凝胶法制备了热致变色钨掺杂二氧化钒薄膜。首先将乙酰丙酮氧钒和氯化钨置于甲醇溶液中反应制备出前驱体,然后将前驱物旋涂在衬底基材上。最后在氩气氛围中、600 ℃进行退火。同时,对所制备的二氧化钒薄膜进行了XRD、XPS、SEM、UV和WCA等表征和测试。结果表明,钨掺杂二氧化钒薄膜颗粒尺寸范围从30～150 nm,薄膜的表面展现出优异的亲水性,其静态水接触角为12°。根据光学测试,钨掺杂VO2薄膜表现出优异的光学性能与可见光调节效率(Tlum,s = 80.75%,Tlum,m = 79.24%)和优良的太阳能调节效率(ΔTsol = 9.10%,Tsol,s = 81.40%,Tsol,m= 72.30%)。VO2薄膜相变表现出可适用的相变温度:在钨掺杂摩尔量为2%时,其相变温度为32 ℃。
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| 关 键 词： | 二氧化钒 溶胶凝胶法 超亲水 |
Preparation and Characterization of Tungsten-doped Vanadium Dioxide Thin Films with Self-cleaning and Energy-saving Functions |
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| SUN Junmei,LIANG Zihui,ZHAO Li,DONG Binghai and WANG Shimin.Preparation and Characterization of Tungsten-doped Vanadium Dioxide Thin Films with Self-cleaning and Energy-saving Functions[J].Materials Review,2018,32(Z2):134-139, 146. |
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| Authors: | SUN Junmei LIANG Zihui ZHAO Li DONG Binghai and WANG Shimin |
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| Affiliation: | College of Pharmacy and Biological Engineering, Chengdu University, Chengdu 610106,Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Hubei University, Wuhan 430062;Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei University, Wuhan 430062;Hubei Key Laboratory of Polymer Materials, Hubei University, Wuhan 430062,Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Hubei University, Wuhan 430062;Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei University, Wuhan 430062;Hubei Key Laboratory of Polymer Materials, Hubei University, Wuhan 430062,Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Hubei University, Wuhan 430062;Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei University, Wuhan 430062;Hubei Key Laboratory of Polymer Materials, Hubei University, Wuhan 430062 and Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Hubei University, Wuhan 430062;Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Hubei University, Wuhan 430062;Hubei Key Laboratory of Polymer Materials, Hubei University, Wuhan 430062 |
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| Abstract: | |
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| Keywords: | vanadium dioxide sol-gel method superhydrophibic |
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