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Preparation of (R)-and (S)-2-Allyl-1,3,2-Dinaphtho(α,β)[d.f]dioxaborepin and Their Reactions with Aldehydes
引用本文:Liu De-jun,Shan Zi-xing ,Wang Guo-ping,Qin Jin-gui College of Chemistry and Molecular Sciences,Wuhan University,Wuhan ,Hubei,China.Preparation of (R)-and (S)-2-Allyl-1,3,2-Dinaphtho(α,β)[d.f]dioxaborepin and Their Reactions with Aldehydes[J].武汉大学学报:自然科学英文版,2003,8(4).
作者姓名:Liu De-jun  Shan Zi-xing   Wang Guo-ping  Qin Jin-gui College of Chemistry and Molecular Sciences  Wuhan University  Wuhan  Hubei  China
作者单位:Liu De-jun,Shan Zi-xing ,Wang Guo-ping,Qin Jin-gui College of Chemistry and Molecular Sciences,Wuhan University,Wuhan 430072,Hubei,China
基金项目:SupportedbytheNationalNaturalScienceFoundationofChina (2 9972 0 33)
摘    要:0 IntroductionEnantiopure 1,1′ bi 2 naphtholspossessingC2 chiralityhaveprovedtobeversatilechiralauxiliariesinanumberofasym metricreactions1 \|6] .Althoughsomeboroncompoundsofthemhavebeenprepared7 1 6] ,chemistryoftheirallylboranederivativeshasneverbeenreported .Toexplorepossibilityofapplyingseven memberedcyclicchrialallylboronateesterstoasymmetricsynthesisofchiralβ alkenylalcohols,whichareimportantintermediateinthepreparationofopticallyactivenaturalproducts,werecentlyat temptedtosynthesi…

关 键 词:1  1′-bi-2-naphthyl  allylboronate

Preparation of (R)- and (S)-2-Allyl-1,3,2-Dinaphtho(α,β)[d.f]dioxaborepin and Their Reactions with Aldehydes
Liu De-jun,Shan Zi-xing,Wang Guo-ping,Qin Jin-gui.Preparation of (R)- and (S)-2-Allyl-1,3,2-Dinaphtho(α,β)[d.f]dioxaborepin and Their Reactions with Aldehydes[J].Wuhan University Journal of Natural Sciences,2003,8(4).
Authors:Liu De-jun  Shan Zi-xing  Wang Guo-ping  Qin Jin-gui
Abstract:
Keywords:1  1'-bi-2-naphthyl allylboronate  preparation  asymmetric allylation
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