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Estimation of nitric oxide emissions from an internal combustion engine
Authors:John D. Butler  David M. Thorne
Abstract:The analysis of nitric oxide, the principal nitrogen oxide in raw exhaust gas, is described by two different techniques. Concordance of analytical determinations using the Saltzman colorimetric solution method with the gas phase chemiluminescence method is demonstrated. By dilution of exhaust gas from an internal combustion engine with nitrogen it is shown that gas samples can be stored for periods of at least 30 min without significant change in sample composition with respect to nitric oxide. This procedure enables reliable estimations of nitric oxide in exhaust gas contained in a sealed transportable vessel to be performed at sites remote from the sample point, without introducing errors due to loss of nitric oxide by chemical reaction in the time between sampling and analysis.
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