Electrochemistry at capped platinum nanoparticle Langmuir Blodgett films: A study of the influence of platinum amount and of number of LB layers |
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Authors: | Sara Cavaliere-Jaricot Arnaud Etcheberry Michel Herlem Henri Perez |
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Affiliation: | a Institut Lavoisier (IREM-CNRS, UMR 8637), Université de Versailles Saint Quentin en Yvelines, 45 av. des Etats-Unis, 78035 Versailles Cedex, France b Laboratoire Francis Perrin, CEA/DSM/DRECAM/SPAM-CNRS URA 2453, Bât. 522, 91191 Gif-sur-Yvette, France |
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Abstract: | Platinum nanoparticles (n-Pt), over-grafted with 2-thiophenecarbonyl chloride are assembled on gold electrodes, by the Langmuir Blodgett (LB) technique using behenic acid (BHA) as promoting agent. These layers are electrochemically active without any preliminary activation. The Fe(CN)6]3−/4− redox couple was used as electrochemical probe. This paper reports on the influence of the number of deposited LB layers, and the n-Pt density on the electrochemical response. n-Pt density was modified by the change of the “BHA/n-Pt” ratio. Cyclic voltammograms of “Fe(CN)6]3−/4−” were observed whatever the coating conditions. As soon as the first layer was deposited the electrochemical response was associated to the n-Pt coverage, its response slightly increased up to a steady state for five or seven layers. As expected, the increase of the Pt density favored the increase of the current density. XPS analysis performed before and after electrochemical cycling showed that 4-mercaptoaniline capped platinum nanoparticles, and their over grafting were chemically and electrochemically stable. Analysis of influence of the number or the n-Pt density of the layers showed that the electrochemically active part of LB electrodes was provided by the last layer plus a part of the underlying one. |
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Keywords: | Capped platinum nanoparticles 2-Thiophenecarbonyl chloride over-grafting Langmuir Blodgett (LB) technique Electron transfer LB heterostructures XPS |
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