Abstract: | The hydrothermal crystallization in Nd2O31bGeO21bNaOH1bH2O system is investigated. The single crystals of NaNd3[GeO4]2(OH)2, Na4,67[GeO4]3O, NaNd3Ge4O13, Nd2GeO5, Nd2Ge2O7, Nd(OH)3, Na4Ge9O20,Na2GeO3·H2O are obtained. The phase diagram of the crystallization fields in the system under consideration is built. The germanates synthesized are stadied by X-Ray analysis and IR-spectroscopy. |