Synthesis and characterization of high-density LiFePO4/C composites as cathode materials for lithium-ion batteries |
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Authors: | Zhao-Rong Chang Hao-Jie Lv Hua-Ji Li Haijiang Wang |
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Affiliation: | a College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007, PR China b Institute for Fuel Cell Innovation, National Research Council of Canada, Vancouver, BC, Canada V6T 1W5 |
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Abstract: | To achieve a high-energy-density lithium electrode, high-density LiFePO4/C composite cathode material for a lithium-ion battery was synthesized using self-produced high-density FePO4 as a precursor, glucose as a C source, and Li2CO3 as a Li source, in a pipe furnace under an atmosphere of 5% H2-95% N2. The structure of the synthesized material was analyzed and characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). The electrochemical properties of the synthesized LiFePO4/carbon composite were investigated by cyclic voltammetry (CV) and the charge/discharge process. The tap-density of the synthesized LiFePO4/carbon composite powder with a carbon content of 7% reached 1.80 g m−3. The charge/discharge tests show that the cathode material has initial charge/discharge capacities of 190.5 and 167.0 mAh g−1, respectively, with a volume capacity of 300.6 mAh cm−3, at a 0.1C rate. At a rate of 5C, the LiFePO4/carbon composite shows a high discharge capacity of 98.3 mAh g−1 and a volume capacity of 176.94 mAh cm−3. |
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Keywords: | LiFePO4/C Lithium battery High-density Conductivity |
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