| 吡嗪基联吡啶锌配位聚合物的结构及发光性质 |
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| 引用本文： | 宋娟,杨守洁,任传清,史娟,葛红光,姜敏.吡嗪基联吡啶锌配位聚合物的结构及发光性质[J].人工晶体学报,2017,46(7):1385-1388. |
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| 作者姓名： | 宋娟 杨守洁 任传清 史娟 葛红光 姜敏 |
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| 作者单位： | 陕西理工大学化学与环境科学学院,陕西省催化基础与应用重点实验室,汉中 723001 |
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| 基金项目： | 国家自然?蒲Щ?21373132);陕西理工大学博士科研启动基金(SLGKYQD2-08);陕西省科技厅自然科学基金项目(2015JM2060) |
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| 摘 要： | 以2,6-双(2-吡嗪基)-4,4'-联吡啶为配体,对苯二甲酸为辅助配体,水热条件下合成了锌配位聚合物Zn(dpb)(p-bdc)]n·0.5n(dpb),并用元素分析、红外光谱、X射线单晶衍射对此配位聚合物进行了测试分析.单晶结构解析表明,它是通过对苯二甲酸桥连锌离子形成一维链结构的配位聚合物.此外,对配体及配位聚合物的荧光进行了研究.
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| 关 键 词： | 锌 晶体结构 水热合成 光学性质 |
Crystal Structure and Luminescence of Zinc Coordination Polymer Based on Pyrazinyl Pyridine Ligand |
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| SONG Juan,YANG Shou-jie,REN Chuan-qing,SHI Juan,GE Hong-guang,JIANG Min.Crystal Structure and Luminescence of Zinc Coordination Polymer Based on Pyrazinyl Pyridine Ligand[J].Journal of Synthetic Crystals,2017,46(7):1385-1388. |
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| Authors: | SONG Juan YANG Shou-jie REN Chuan-qing SHI Juan GE Hong-guang JIANG Min |
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| Abstract: | A zinc coordination polymer, Zn(dpb)(p-bdc)]n·0.5n(dpb) has been hydrothermally synthesized by reaction of zinc chloride with 2,6-di(pyrazin-2-yl)-4,4'-bipyridine and p-H2bdc ligands.The coordination polymer was structurally characterized by elemental analyses, IR, and TGA.X-ray single crystal diffraction analysis shows that the coordination polymer is a one-dimension chain structure.Additionally, the fluorescence of free dpb ligand and zinc coordination polymer were also investigated. |
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| Keywords: | A zinc coordination polymer [Zn(dpb)(p-bdc)]n·0 5n(dpb) has been hydrothermally synthesized by reaction of zinc chloride with 2 6-di(pyrazin-2-yl)-4 4'-bipyridine and p-H2bdc ligands The coordination polymer was structurally characterized by elemental analyses IR and TGA X-ray single crystal diffraction analysis shows that the coordination polymer is a one-dimension chain structure Additionally the fluorescence of free dpb ligand and zinc coordination polymer were also investigated |
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