| 一种用于染料敏化太阳能电池的插层磷酸锆复合凝胶电解质 |
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| 引用本文： | 韩黎,王宁,何泓材,孔德廷,陈海军,孙满龙,赵伟民.一种用于染料敏化太阳能电池的插层磷酸锆复合凝胶电解质[J].纳米科技,2011(3):61-65. |
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| 作者姓名： | 韩黎 王宁 何泓材 孔德廷 陈海军 孙满龙 赵伟民 |
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| 作者单位： | 电子科技大学电子薄膜与集成器件国家重点实验室;东莞宏威数码机械有限公司; |
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| 摘 要： | 介绍了一种新型的应用于染料敏化太阳能电池的插层磷酸锆复合凝胶电解质。磷酸锆通过插层反应使其层间距增大到2.04nm,然后加入到聚氧化乙烯(PEO)凝胶中得到复合凝胶电解质。插层磷酸锆的添加极大地提高了电解质在常温下的离子电导率和离子扩散系数。由该凝胶电解质组装的染料敏化太阳能电池获得了6.61%的光转化效率(AM 1.5G 100mW·cm-2 25℃)。
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| 关 键 词： | 插层磷酸锆 复合凝胶电解质 染料敏化太阳能电池 离子扩散系数 电导率 |
Composite Gel Electrolyte with Layered a-ZrP for Dye-sensitized Solar Cells |
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| Authors: | HAN Li WANG Ning HE Hong-cai KONG De-ting CHEN Hai-jun SUN Man-long ZHAO Wei-min |
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| Affiliation: | HAN Li1,WANG Ning1,HE Hong-cai1,KONG De-ting1,CHEN Hai-jun1,SUN Man-long2,ZHAO Wei-min2(1.State Key Laboratoty of Electronic Thin Films and Integrated Devices,University of Electronic Science and Technology of China,Chengdu 610054,China)(2.Dongguan Anwell Digital Machinery Co.Ltd,Dongguan 523081,China) |
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| Abstract: | Present a new intercalated zirconium phosphate composite gel electrolyte for dye-sensitized solar cells(DSSC).The spacing of zirconium phosphate reached to 2.04 nm with intercalated reaction,and the composite gel electrolyte was obtained by adding the Zirconium phosphate into polyethlene oxide(PEO) polymer.The ionic electrical conductivity and diffusion coefficient of the the electrolyte was improved by adding intercalated zirconium phosphate at room temperature.The DSSC with 5 wt% ZrP-BA-PC addition into t... |
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| Keywords: | intercalated a-Zireonium phosphate composite polymer electrolyte dye-sensitized solar cells diffusion coefficient ionic conductivity |
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