Stability of oil-in-water emulsions by SDS compound |
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Authors: | Feng Rong Zhiyong Hu |
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Affiliation: | 1. College of Petroleum Engineering, Liaoning Shihua University, Fushun Liaoning, P. R. Chinarfsongone@126.com;3. College of Architecture Storage Engineering, China University of Petroleum(East China), Qingdao, Shandong, P. R. China |
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Abstract: | AbstractSurfactants are often required to reduce emulsion viscosity and heavy-oil flow resistance in pipelines, thereby forming a stable oil-in-water emulsion under shear stress. This study aimed to quantitatively discuss and analyze the stability of oil-in-water emulsions and characterize them through the initial viscosity change rate K. The value of K was obtained based on the oil-rich-phase viscosity curves of oil-in-water emulsions comprising sodium dodecyl sulfate (SDS), heavy oil, and water at different time points. Results showed that a smaller K corresponded to a more stable emulsion according to analysis of the effect of the compound system on emulsion stability and the synergistic mechanism. We then combined with 1-pentanol and octyldecyl glucoside (APG0810) with SDS. Results showed that the K values of the emulsions decreased from 19.457 to 6.284, and 19.457 to 5.834, respectively, after mixing 6% 1-pentanol and 0.4% APG, respectively, with 0.14% SDS. Then, 0.14% SDS was compared with 1.2% a mass fraction of each of the three additives to form a compound system, and the K values were found to follow the trend K1-pentanol/SDS > KAPG/SDS. Thus, the stability of APG/SDS oil-in-water emulsion was better than that of 1-pentanol/SDS emulsion. |
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Keywords: | initial viscosity change rate oil-in-water emulsion oil-rich phase sds compound the stability |
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